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- W2799694704 abstract "Lithium intercalation into graphite is one of the electrochemically best studied solid-state reactions, and its application in lithium-ion batteries was a pioneering step in the development of advanced electrochemical storage devices. Therefore, one might expect that virtually any aspect of this important reaction has been examined both qualitatively and quantitatively. All the more, it is surprising that there are only a few experimental studies on the volume expansion of graphite, especially under cycling conditions. To the best of our knowledge, there exists no comprehensive set of structural data as a function of lithium content. Here, we present this missing information using combined results from electrochemical testing and operando X-ray diffraction. The changes in lattice parameters and unit cell volume are examined and related to the different intercalation stages and phase transition regimes. A total volume expansion (from space-group-independent evaluation) of 13.2% is observed when C6 is fully..." @default.
- W2799694704 created "2018-05-17" @default.
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- W2799694704 date "2018-04-04" @default.
- W2799694704 modified "2023-10-17" @default.
- W2799694704 title "Volume Changes of Graphite Anodes Revisited: A Combined <i>Operando</i> X-ray Diffraction and <i>In Situ</i> Pressure Analysis Study" @default.
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- W2799694704 doi "https://doi.org/10.1021/acs.jpcc.8b01873" @default.
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