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- W2799992920 endingPage "9324" @default.
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- W2799992920 abstract "Abstract Centrohexaindane was converted into its T d ‐symmetrical 2,3,6,7,10,11,14,15,20,21,26,27‐dodecabromo and ‐dodecaiodo derivatives using N ‐bromo‐ and N ‐iodosuccinimide, respectively, in the presence of trifluoromethanesulfonic acid as a catalyst in single, highly efficient steps. Sonication or microwave irradiation was indispensable to enforce exhaustive halogenation of the twelve equivalent peripheral positions of this Cartesian polyaromatic hydrocarbon. Despite their extremely poor solubility in most organic solvents, the new dodecahalo derivatives were fully characterized, including single crystal X‐ray structure analysis. Subsequent Pd 0 ‐catalyzed twelve‐fold C−C cross‐coupling reactions furnished the corresponding dodecamethyl, dodeca(phenylethynyl) and dodecaphenyl derivatives in good to excellent yields. The latter hydrocarbon was also analyzed by X‐ray diffraction." @default.
- W2799992920 created "2018-05-17" @default.
- W2799992920 creator A5004375398 @default.
- W2799992920 creator A5009050687 @default.
- W2799992920 creator A5029807989 @default.
- W2799992920 creator A5060760495 @default.
- W2799992920 date "2018-06-20" @default.
- W2799992920 modified "2023-09-30" @default.
- W2799992920 title "Dodecabromo- and Dodecaiodocentrohexaindane:Td-Symmetrical Key Building Blocks for Twelve-Fold Cross-Coupling Reactions and Six-Fold Orthogonal Extension" @default.
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- W2799992920 doi "https://doi.org/10.1002/chem.201801806" @default.
- W2799992920 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29738094" @default.
- W2799992920 hasPublicationYear "2018" @default.
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