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• W2800107534 abstract "Rechargeable hybrid aqueous batteries (ReHABs) have emerged as promising sustainable energy-storage devices because all components are environmentally benign and abundant. In this study, a carbon-wrapped sponge-like Na3 V2 (PO4 )3 nanoparticle (NVP@C) cathode is prepared by a simple pyrosynthesis for use in the ReHAB system with impressive rate capability and high cyclability. A high-resolution X-ray diffraction study confirmed the formation of pure Na ion superionic conductor (NASICON) NVP with rhombohedral structure. When tested in the ReHAB system, the NVP@C demonstrated high rate capability (66 mAh g-1 at 32 C) and remarkable cyclability over 1000 cycles (about 72 % of the initial capacity is retained at 30 C). Structural transformation and oxidation change studies of the electrode evaluated by using in situ synchrotron X-ray diffraction and ex situ X-ray photoelectron spectroscopy, respectively, confirmed the high reversibility of the NVP@C electrode in the ReHAB system through a two-phase reaction. The combined strategy of nanosizing and carbon-wrapping in the NVP particles is responsible for the remarkable electrochemical properties. The pyrosynthesis technique appears to be a promising and feasible approach to prepare a high-performance electrode for safe and low-cost ReHAB systems as nextgeneration large-scale energy storage devices." @default.
• W2800107534 created "2018-05-17" @default.
• W2800107534 creator A5001809722 @default.
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• W2800107534 date "2018-06-21" @default.
• W2800107534 modified "2023-10-12" @default.
• W2800107534 title "Pyrosynthesis of Na ₃ V ₂ (PO ₄ ) ₃ @C Cathodes for Safe and Low‐Cost Aqueous Hybrid Batteries" @default.
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• W2800107534 doi "https://doi.org/10.1002/cssc.201800724" @default.
• W2800107534 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29708309" @default.
• W2800107534 hasPublicationYear "2018" @default.
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