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• W2800162334 endingPage "2928" @default.
• W2800162334 startingPage "2925" @default.
• W2800162334 abstract "An expeditious synthetic route to access structurally diverse 1,4,5,6-tetrahydropyrimidines via domino ring-opening cyclization of activated aziridines with α-acidic isocyanides has been established. The transformation proceeds via Lewis acid mediated SN2-type ring opening of activated aziridines with α-carbanion of the isocyanides followed by a concomitant 6-endo-dig cyclization in a domino fashion to furnish the 1,4,5,6-tetrahydropyrimidine derivatives in excellent yields (up to 84%) and also in diastereo- and enantiomerically pure form (dr >99:1, ee >99%)." @default.
• W2800162334 created "2018-05-17" @default.
• W2800162334 creator A5006491428 @default.
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• W2800162334 date "2018-05-08" @default.
• W2800162334 modified "2023-09-27" @default.
• W2800162334 title "Stereospecific Synthesis of 1,4,5,6-Tetrahydropyrimidines via Domino Ring-Opening Cyclization of Activated Aziridines with α-Acidic Isocyanides" @default.
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• W2800162334 doi "https://doi.org/10.1021/acs.orglett.8b00986" @default.
• W2800162334 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29738257" @default.
• W2800162334 hasPublicationYear "2018" @default.
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