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- W2800320007 abstract "The catalytic [5 + 1] annulation/5-exo-cyclization reaction of amidines with diynes is reported herein. This protocol provides highly atom-economical access to fabricate two nitrogen-containing heterocycles in one step with high efficiency and selectivity. Significantly, this reaction represents the first example of using diyne as a one-carbon reaction partner in C-H functionalization. Kinetic isotope effects suggested that the catalytic cycle of this reaction is initiated by the cleavage of the ortho C-H bond in the N-phenyl ring of amidines, which is likely involved in the rate-limiting step. Calculations based on density functional theory (DFT) indicated that C-H activation and the formation of Rh(V) species via 5-exo-cyclization could be vital processes for this cascade transformation." @default.
- W2800320007 created "2018-05-17" @default.
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- W2800320007 date "2018-05-14" @default.
- W2800320007 modified "2023-10-17" @default.
- W2800320007 title "Rhodium(III)-Catalyzed Cascade [5 + 1] Annulation/5-exo-Cyclization Initiated by C–H Activation: 1,6-Diynes as One-Carbon Reaction Partners" @default.
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- W2800320007 doi "https://doi.org/10.1021/acs.orglett.8b01105" @default.
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