Matches in SemOpenAlex for { <https://semopenalex.org/work/W2800374429> ?p ?o ?g. }
- W2800374429 endingPage "5753" @default.
- W2800374429 startingPage "5743" @default.
- W2800374429 abstract "We synthesized and thoroughly characterized a new family of diarylethene-conjugated mononuclear Ru(II)-terpyridine complexes and investigated in detail their photophysical, electrochemical, and spectroelectrochemical behaviors. Interestingly, the compounds show moderately strong room-temperature luminescence predominantly from their 3MLCT state with luminescence lifetime varying between 8.43 and 22.82 ns. Because of the presence of diarylethene unit, all the monometallic complexes underwent trans-to-cis photoisomerization upon interaction with UV light with substantial changes in their absorption and luminescence spectra. Reverting back from the cis to the trans form is also made possible upon treatment with visible light or by heat. Trans-to-cis isomerization leads to almost complete quenching of luminescence, while backward cis-to-trans isomerization gives rise to restoration of the original luminescence for all the complexes. Thus, on-off and off-on emission switching was made possible upon successive interaction of the complexes with UV and visible light. Computational investigation involving density functional theory (DFT) and time-dependent DFT methods was done for proper assignment of the experimental absorption and emission spectral bands in the complexes. Finally, experimentally observed trend on the absorption and emission spectral behaviors of the complexes upon photoisomerization was also compared with the calculated results." @default.
- W2800374429 created "2018-05-17" @default.
- W2800374429 creator A5003482591 @default.
- W2800374429 creator A5004258293 @default.
- W2800374429 creator A5058362229 @default.
- W2800374429 creator A5089314567 @default.
- W2800374429 date "2018-04-27" @default.
- W2800374429 modified "2023-09-24" @default.
- W2800374429 title "Synthesis, Structural Characterization, and Luminescence Switching of Diarylethene-Conjugated Ru(II)-Terpyridine Complexes by trans–cis Photoisomerization: Experimental and DFT/TD-DFT Investigation" @default.
- W2800374429 cites W129845126 @default.
- W2800374429 cites W1970393749 @default.
- W2800374429 cites W1970499578 @default.
- W2800374429 cites W1970952020 @default.
- W2800374429 cites W1974894118 @default.
- W2800374429 cites W1975159473 @default.
- W2800374429 cites W1976370544 @default.
- W2800374429 cites W1980532895 @default.
- W2800374429 cites W1986227479 @default.
- W2800374429 cites W1990913686 @default.
- W2800374429 cites W1993123308 @default.
- W2800374429 cites W1993787245 @default.
- W2800374429 cites W2000231152 @default.
- W2800374429 cites W2002574462 @default.
- W2800374429 cites W2009542925 @default.
- W2800374429 cites W2010119322 @default.
- W2800374429 cites W2010363805 @default.
- W2800374429 cites W2015404771 @default.
- W2800374429 cites W2016875452 @default.
- W2800374429 cites W2017908410 @default.
- W2800374429 cites W2022646701 @default.
- W2800374429 cites W2023271753 @default.
- W2800374429 cites W2033945824 @default.
- W2800374429 cites W2036431718 @default.
- W2800374429 cites W2036769624 @default.
- W2800374429 cites W2038358840 @default.
- W2800374429 cites W2039307253 @default.
- W2800374429 cites W2040991637 @default.
- W2800374429 cites W2044756363 @default.
- W2800374429 cites W2044978453 @default.
- W2800374429 cites W2045540077 @default.
- W2800374429 cites W2052587503 @default.
- W2800374429 cites W2052752040 @default.
- W2800374429 cites W2054033384 @default.
- W2800374429 cites W2058896166 @default.
- W2800374429 cites W2065779362 @default.
- W2800374429 cites W2068423208 @default.
- W2800374429 cites W2080823038 @default.
- W2800374429 cites W2082248150 @default.
- W2800374429 cites W2082726978 @default.
- W2800374429 cites W2084017605 @default.
- W2800374429 cites W2086044791 @default.
- W2800374429 cites W2088621985 @default.
- W2800374429 cites W2090329067 @default.
- W2800374429 cites W2090674105 @default.
- W2800374429 cites W2094408698 @default.
- W2800374429 cites W2105853391 @default.
- W2800374429 cites W2108359741 @default.
- W2800374429 cites W2109672445 @default.
- W2800374429 cites W2114683411 @default.
- W2800374429 cites W2115415075 @default.
- W2800374429 cites W2128492772 @default.
- W2800374429 cites W2130329306 @default.
- W2800374429 cites W2143981217 @default.
- W2800374429 cites W2155600484 @default.
- W2800374429 cites W2165289729 @default.
- W2800374429 cites W2167450294 @default.
- W2800374429 cites W2168504688 @default.
- W2800374429 cites W2192191407 @default.
- W2800374429 cites W2312895145 @default.
- W2800374429 cites W2313355918 @default.
- W2800374429 cites W2313564679 @default.
- W2800374429 cites W2314586527 @default.
- W2800374429 cites W2317604061 @default.
- W2800374429 cites W2317762889 @default.
- W2800374429 cites W2319043900 @default.
- W2800374429 cites W2319774976 @default.
- W2800374429 cites W2323164738 @default.
- W2800374429 cites W2325474276 @default.
- W2800374429 cites W2330569460 @default.
- W2800374429 cites W2331810137 @default.
- W2800374429 cites W2335506970 @default.
- W2800374429 cites W2408266362 @default.
- W2800374429 cites W2519687291 @default.
- W2800374429 cites W2729113812 @default.
- W2800374429 cites W2949485030 @default.
- W2800374429 cites W2950713969 @default.
- W2800374429 cites W3022457912 @default.
- W2800374429 cites W4234522627 @default.
- W2800374429 cites W4239957262 @default.
- W2800374429 cites W4256166569 @default.
- W2800374429 cites W49952862 @default.
- W2800374429 cites W2038656286 @default.
- W2800374429 doi "https://doi.org/10.1021/acs.inorgchem.7b03096" @default.
- W2800374429 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29701476" @default.
- W2800374429 hasPublicationYear "2018" @default.
- W2800374429 type Work @default.
- W2800374429 sameAs 2800374429 @default.
- W2800374429 citedByCount "25" @default.