Matches in SemOpenAlex for { <https://semopenalex.org/work/W2800376485> ?p ?o ?g. }
- W2800376485 abstract "The absolute photoionization spectrum of the hydroxyl (OH) radical from 12.513 to 14.213 eV was measured by multiplexed photoionization mass spectrometry with time-resolved radical kinetics. Tunable vacuum ultraviolet (VUV) synchrotron radiation was generated at the Advanced Light Source. OH radicals were generated from the reaction of O(1D) + H2O in a flow reactor in He at 8 Torr. The initial O(1D) concentration, where the atom was formed by pulsed laser photolysis of ozone, was determined from the measured depletion of a known concentration of ozone. Concentrations of OH and O(3P) were obtained by fitting observed time traces with a kinetics model constructed with literature rate coefficients. The absolute cross section of OH was determined to be σ(13.436 eV) = 3.2 ± 1.0 Mb and σ(14.193 eV) = 4.7 ± 1.6 Mb relative to the known cross section for O(3P) at 14.193 eV. The absolute photoionization spectrum was obtained by recording a spectrum at a resolution of 8 meV (50 meV steps) and scaling to the single-energy cross sections. We computed the absolute VUV photoionization spectrum of OH and O(3P) using equation-of-motion coupled-cluster Dyson orbitals and a Coulomb photoelectron wave function and found good agreement with the observed absolute photoionization spectra." @default.
- W2800376485 created "2018-05-17" @default.
- W2800376485 creator A5017686746 @default.
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- W2800376485 date "2018-05-08" @default.
- W2800376485 modified "2023-10-16" @default.
- W2800376485 title "Vacuum ultraviolet photoionization cross section of the hydroxyl radical" @default.
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- W2800376485 doi "https://doi.org/10.1063/1.5024249" @default.
- W2800376485 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29764149" @default.
- W2800376485 hasPublicationYear "2018" @default.
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