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- W2800476811 endingPage "6461" @default.
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- W2800476811 abstract "In this Perspective, we outline recent examples of homogeneous transition-metal hydrogen transfer catalysts for which functionality within the complex’s outer coordination sphere influences the outcome of a reaction. Secondary-sphere groups are often applied to hydrogen transfer reactions, but their specific role during catalysis is not always well-understood. New experimental and theoretical work details the complexity associated with predicting secondary-sphere interactions and therefore designing improved catalysts. This Perspective highlights examples of catalysts containing secondary-sphere groups that (1) accelerate a key turnover-limiting step such as H2 heterolysis or hydride transfer, (2) limit competing catalytic cycles, (3) prevent catalyst decomposition, and/or (4) provide access to new catalysts through postmetalation modifications. The examples described herein emphasize numerous roles of the secondary sphere in hydrogen transfer catalysis and illustrate how the optimal use of these interactions is predicated on the analyses of key reaction intermediates in a catalytic reaction." @default.
- W2800476811 created "2018-05-17" @default.
- W2800476811 creator A5009251963 @default.
- W2800476811 creator A5087072672 @default.
- W2800476811 date "2018-04-30" @default.
- W2800476811 modified "2023-10-18" @default.
- W2800476811 title "Hydrogen Transfer Catalysis beyond the Primary Coordination Sphere" @default.
- W2800476811 cites W1198400294 @default.
- W2800476811 cites W1488691481 @default.
- W2800476811 cites W1508200337 @default.
- W2800476811 cites W1518331094 @default.
- W2800476811 cites W1901089361 @default.
- W2800476811 cites W1964512540 @default.
- W2800476811 cites W1966472421 @default.
- W2800476811 cites W1967087933 @default.
- W2800476811 cites W1968670039 @default.
- W2800476811 cites W1969002848 @default.
- W2800476811 cites W1970618615 @default.
- W2800476811 cites W1973069192 @default.
- W2800476811 cites W1975506590 @default.
- W2800476811 cites W1979640190 @default.
- W2800476811 cites W1983390949 @default.
- W2800476811 cites W1983809335 @default.
- W2800476811 cites W1984877122 @default.
- W2800476811 cites W1985490103 @default.
- W2800476811 cites W1986383124 @default.
- W2800476811 cites W1987832365 @default.
- W2800476811 cites W1989859901 @default.
- W2800476811 cites W1990863674 @default.
- W2800476811 cites W1991822543 @default.
- W2800476811 cites W199292962 @default.
- W2800476811 cites W1993954445 @default.
- W2800476811 cites W1994884720 @default.
- W2800476811 cites W1996580794 @default.
- W2800476811 cites W1996610836 @default.
- W2800476811 cites W1997623752 @default.
- W2800476811 cites W1997857215 @default.
- W2800476811 cites W2002096928 @default.
- W2800476811 cites W2002122522 @default.
- W2800476811 cites W2004242300 @default.
- W2800476811 cites W2004560459 @default.
- W2800476811 cites W2004837355 @default.
- W2800476811 cites W2011463833 @default.
- W2800476811 cites W2012092497 @default.
- W2800476811 cites W2013354669 @default.
- W2800476811 cites W2015439558 @default.
- W2800476811 cites W2015784886 @default.
- W2800476811 cites W2017924938 @default.
- W2800476811 cites W2019943654 @default.
- W2800476811 cites W2022005947 @default.
- W2800476811 cites W2023174370 @default.
- W2800476811 cites W2024872256 @default.
- W2800476811 cites W2026637040 @default.
- W2800476811 cites W2027950614 @default.
- W2800476811 cites W2028851759 @default.
- W2800476811 cites W2032294243 @default.
- W2800476811 cites W2033288172 @default.
- W2800476811 cites W2037374692 @default.
- W2800476811 cites W2038071113 @default.
- W2800476811 cites W2039971454 @default.
- W2800476811 cites W2040371083 @default.
- W2800476811 cites W2044520616 @default.
- W2800476811 cites W2045411127 @default.
- W2800476811 cites W2046705003 @default.
- W2800476811 cites W2050828896 @default.
- W2800476811 cites W2051243557 @default.
- W2800476811 cites W2051508281 @default.
- W2800476811 cites W2054976385 @default.
- W2800476811 cites W2055518409 @default.
- W2800476811 cites W2059557791 @default.
- W2800476811 cites W2061382464 @default.
- W2800476811 cites W2062345835 @default.
- W2800476811 cites W2063796154 @default.
- W2800476811 cites W2065818181 @default.
- W2800476811 cites W2067854056 @default.
- W2800476811 cites W2069324431 @default.
- W2800476811 cites W2071635598 @default.
- W2800476811 cites W2075456034 @default.
- W2800476811 cites W2077427344 @default.
- W2800476811 cites W2084935596 @default.
- W2800476811 cites W2085471965 @default.
- W2800476811 cites W2085595472 @default.
- W2800476811 cites W2088382740 @default.
- W2800476811 cites W2090130090 @default.
- W2800476811 cites W2091449628 @default.
- W2800476811 cites W2093581449 @default.
- W2800476811 cites W2093789466 @default.
- W2800476811 cites W2095417590 @default.
- W2800476811 cites W2114082414 @default.
- W2800476811 cites W2117011228 @default.
- W2800476811 cites W2120410660 @default.
- W2800476811 cites W2124810596 @default.
- W2800476811 cites W2129758402 @default.
- W2800476811 cites W2131015424 @default.
- W2800476811 cites W2131400546 @default.
- W2800476811 cites W2131973597 @default.
- W2800476811 cites W2132289978 @default.
- W2800476811 cites W2134019393 @default.