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- W2800536104 abstract "Abstract In this work, a facile synthetic method for site-selectively Pt-decorated PdPt bimetallic nanosheets (S-Pt-PdPtBN) has been described. The size, structure, and composition distribution of the synthesized S-Pt-PdPtBN were determined by transmission electron microscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. The electrocatalytic activity of these bimetallic nanosheets was examined for the oxidation of methanol in an acidic solution. The electrochemically active surface area (ECSA) of S-Pt-PdPtBN was 0.842 cm2. This value is slightly lower than the ECSA (1.012 cm2) of the commercial Pt/C (Alpha, Pt 10%) electrode. Interestingly, even though the ECSA of the S-Pt-PdPtBN/C was smaller than that of the commercial Pt/C, the forward peak current density of the former (2.95 mA cm−2) was ca. 1.5 times higher than that of the latter (2.05 mA cm−2). Moreover, the current density of the S-Pt-PdPtBN/C catalysts was high even after 800 s of continuous electrocatalysis at 0.5 V. This current density is six times that of commercial Pt/C catalysts. Thus, the synthesized S-Pt-PdPtBN exhibited significantly enhanced electrocatalytic activity and better stability than the commercial Pt/C catalyst for methanol oxidation." @default.
- W2800536104 created "2018-05-17" @default.
- W2800536104 creator A5022377679 @default.
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- W2800536104 date "2018-08-01" @default.
- W2800536104 modified "2023-09-24" @default.
- W2800536104 title "Site-selectively Pt-decorated PdPt bimetallic nanosheets characterized by electrocatalytic property for methanol oxidation" @default.
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- W2800536104 doi "https://doi.org/10.1016/j.matchemphys.2018.04.072" @default.
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