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• W2800544909 startingPage "6186" @default.
• W2800544909 abstract "A Cu(I)-catalyzed cross-coupling reaction of terminal alkynes and bis(trimethylsilyl)diazomethane is reported. Mechanistically, the reaction is based on the recently developed cross-coupling reactions through metal-carbene migratory insertion. This reaction provides an efficient synthetic method for 1,1-disilyl allenes. Subsequent transformations of 1,1-disilyl allenes are investigated, which show diverse reactivities of these allenes." @default.
• W2800544909 created "2018-05-17" @default.
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• W2800544909 date "2018-05-03" @default.
• W2800544909 modified "2023-10-05" @default.
• W2800544909 title "Cu(I)-Catalyzed Coupling of Bis(trimethylsilyl)diazomethane with Terminal Alkynes: A Synthesis of 1,1-Disilyl Allenes" @default.
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• W2800544909 doi "https://doi.org/10.1021/acs.joc.8b00651" @default.
• W2800544909 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29719960" @default.
• W2800544909 hasPublicationYear "2018" @default.
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