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- W2800552669 endingPage "2674" @default.
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- W2800552669 abstract "The selective aerobic oxidation of nonactivated C–H bonds is a key challenge in both industrial and academic research. The catalytic activity of manganese porphyrins (MnTPPCl) towards the aerobic oxidation of diphenylmethane (DPM) is investigated. Compared with the oxidation‐catalyzed MnTPPCl alone, the conversion of DPM is enhanced ca. 6 times (from 7.0 % to 42.5 %) in the presence of cyclohexene. Some in situ characterizations, such as in situ EPR (electron paramagnetic resonance) spectroscopy and in situ UV/Vis spectroscopy are used to investigate the role of cyclohexene in catalytic oxidation. Mechanistic studies suggest that both high‐valent manganese species and cyclohexenyl alkoxyl radicals are favorable for the formation of the carbon radicals. The enhanced activity is related to the easier generation of secondary carbon radicals, triggered by high‐valent manganese species and cyclohexenyl alkoxyl radicals." @default.
- W2800552669 created "2018-05-17" @default.
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- W2800552669 date "2018-06-04" @default.
- W2800552669 modified "2023-10-01" @default.
- W2800552669 title "Mechanistic Understanding towards the Role of Cyclohexene in Enhancing the Efficiency of Manganese Porphyrin‐Catalyzed Aerobic Oxidation of Diphenylmethane" @default.
- W2800552669 cites W1969183711 @default.
- W2800552669 cites W1976801308 @default.
- W2800552669 cites W1977262764 @default.
- W2800552669 cites W1983321072 @default.
- W2800552669 cites W1985266526 @default.
- W2800552669 cites W1987347658 @default.
- W2800552669 cites W1992280547 @default.
- W2800552669 cites W1999028875 @default.
- W2800552669 cites W2001209398 @default.
- W2800552669 cites W2006197729 @default.
- W2800552669 cites W2012869035 @default.
- W2800552669 cites W2014926653 @default.
- W2800552669 cites W2015705053 @default.
- W2800552669 cites W2020687469 @default.
- W2800552669 cites W2023677223 @default.
- W2800552669 cites W2024420896 @default.
- W2800552669 cites W2033500778 @default.
- W2800552669 cites W2038040189 @default.
- W2800552669 cites W2041947591 @default.
- W2800552669 cites W2047492063 @default.
- W2800552669 cites W2048241319 @default.
- W2800552669 cites W2049477866 @default.
- W2800552669 cites W2050253379 @default.
- W2800552669 cites W2051374888 @default.
- W2800552669 cites W2053752267 @default.
- W2800552669 cites W2060585751 @default.
- W2800552669 cites W2061880307 @default.
- W2800552669 cites W2064845629 @default.
- W2800552669 cites W2068882191 @default.
- W2800552669 cites W2071493717 @default.
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- W2800552669 cites W2082992521 @default.
- W2800552669 cites W2084052917 @default.
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- W2800552669 cites W2087877229 @default.
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- W2800552669 cites W2093773492 @default.
- W2800552669 cites W2095289146 @default.
- W2800552669 cites W2098527406 @default.
- W2800552669 cites W2101930834 @default.
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- W2800552669 cites W2114991443 @default.
- W2800552669 cites W2118145820 @default.
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- W2800552669 cites W2140158011 @default.
- W2800552669 cites W2143386739 @default.
- W2800552669 cites W2152087962 @default.
- W2800552669 cites W2156728663 @default.
- W2800552669 cites W2157513813 @default.
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- W2800552669 cites W2171396825 @default.
- W2800552669 cites W2174809565 @default.
- W2800552669 cites W2247005308 @default.
- W2800552669 cites W2279103949 @default.
- W2800552669 cites W2298641597 @default.
- W2800552669 cites W2320499472 @default.
- W2800552669 cites W2321928492 @default.
- W2800552669 cites W2322153630 @default.
- W2800552669 cites W2335380926 @default.
- W2800552669 cites W2343619009 @default.
- W2800552669 cites W2418557497 @default.
- W2800552669 cites W2612656292 @default.
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- W2800552669 cites W2753279416 @default.
- W2800552669 cites W2761354149 @default.
- W2800552669 cites W2807205225 @default.
- W2800552669 cites W4210302406 @default.
- W2800552669 cites W4230498998 @default.
- W2800552669 cites W4237758940 @default.
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- W2800552669 cites W4240829338 @default.
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- W2800552669 doi "https://doi.org/10.1002/ejic.201800317" @default.
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