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• W2800588621 abstract "Abstract Efficient and general copper catalyzed oxidative cyclization of ortho-vinylaniline has been accomplished employing N-tosylhydrazone as coupling partner. Various substituted quinoline derivatives of biological importance were achieved in good to excellent yield. The important features are the high functional group tolerates, up-gradation to gram scale synthesis and possible one-pot synthesis of quinoline from corresponding carboxaldehyde. Synthetic potential of the obtained quinoline derivatives was demonstrated through C H bond functionalization reaction. Furthermore, preliminary mechanistic investigation revealed the possible generation of non-stabilized diazo compound and imine derivative as potential intermediates as well as copper catalyzed electrocyclic reaction and oxidative aromatization." @default.
• W2800588621 created "2018-05-17" @default.
• W2800588621 creator A5008224808 @default.
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• W2800588621 date "2018-07-01" @default.
• W2800588621 modified "2023-09-26" @default.
• W2800588621 title "Copper catalyzed oxidative coupling of ortho-vinylanilines with N-tosylhydrazones: Efficient synthesis of polysubstituted quinoline derivatives" @default.
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• W2800588621 doi "https://doi.org/10.1016/j.jcat.2018.04.005" @default.
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