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- W2800593603 abstract "An efficient organocatalytic oxidation of racemic secondary alcohols, mediated by sodium hypochlorite (NaOCl) and 2‐azaadamantane N ‐oxyl (AZADO), has been conveniently coupled with a highly stereoselective bioreduction of the intermediate ketone, catalyzed by ketoreductases, in aqueous medium. The potential of this one‐pot two‐step deracemization process has been proven by a large set of structurally different secondary alcohols. Reactions were carried out up to 100 m m final concentration enabling the preparation of enantiopure alcohols with very high isolated yields (up to 98 %). When the protocol was applied to the stereoisomeric rac/meso mixture of diols, these were obtained with very high enantiomeric excesses and diastereomeric ratios (95 % yield, >99 % ee , >99: < 1 dr )." @default.
- W2800593603 created "2018-05-17" @default.
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- W2800593603 date "2018-06-15" @default.
- W2800593603 modified "2023-10-18" @default.
- W2800593603 title "A Straightforward Deracemization of <i>sec</i> -Alcohols Combining Organocatalytic Oxidation and Biocatalytic Reduction" @default.
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- W2800593603 doi "https://doi.org/10.1002/ejoc.201800569" @default.
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