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- W2800593735 abstract "Abstract We demonstrate hierarchically structured, phosphorous (P)-incorporated reduced graphene oxide (HPG) films prepared by a vacuum-filtrated and ice-frozen assembly, freeze-drying and thermal treatment for all solid-state flexible pseudocapacitors. The porous morphology is originated from the interconnected networks of graphene layers and the surface roughness is reduced by the P doping, which results in improving the electrochemical performances. The P=O sites of C-P=O bonding acting as electro-active sites of HPG film are identified by XPS spectra and their charge storage behavior is monitored by in-situ and ex-situ spectrochemical analyses. The HPG film achieves the specific capacitance of 149 F g−1, the capacitance retention of 90.8% from 1 to 30 A g−1, and the cyclic stability of 94.2% over 1000 charging/discharging cycles. Moreover, the pseudocapacitive performances of the HPG films are preserved at the bending state of 120° angle. These excellent electrochemical behaviors are attributed to the unique hierarchical structure and the formation of electro-active of P=O sites by heteroatom doping." @default.
- W2800593735 created "2018-05-17" @default.
- W2800593735 creator A5008529319 @default.
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- W2800593735 date "2018-06-01" @default.
- W2800593735 modified "2023-09-29" @default.
- W2800593735 title "Highly flexible pseudocapacitors of phosphorus-incorporated porous reduced graphene oxide films" @default.
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- W2800593735 doi "https://doi.org/10.1016/j.jpowsour.2018.04.032" @default.
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