FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2800624871> ?p ?o ?g. }

• W2800624871 endingPage "717" @default.
• W2800624871 startingPage "717" @default.
• W2800624871 abstract "This work describes the study of ethylene oligomerization reactions catalyzed by nickel-β-diimine complexes immobilized on β-zeolite, [Si]-MCM-41 (Mobil Composition of Matter 41) and [Si,Al]-MCM-41 modified with an ionic liquid. XRD and N2 adsorption and desorption analyses were used to characterize the modified supports—namely, IL-Zeoβ, IL-MCM-41 and IL-Al-MCM-41—and the data showed that material organization remained intact even after incorporation of ionic liquid. N2 adsorption and desorption analyses suggested that ionic liquid can be confined in pores of support materials. Catalytic properties of synthesized materials were tested under different conditions. The following parameters were varied: Al/Ni molar ratio, temperature, pressure and catalyst loading. The homogeneous catalysts were more active but less selective in ethylene oligomerization, relative to heterogeneous ones, which can be attributed to the effect of confinement suffered by catalyst within channels of the support materials. NiIL-Zeoβ complexes were active, with activities greater than 23 s−1 and selectivities higher than 80% for butenes, including more than 85% of 1-butene. On the other hand, the NiIL-MCM-41 system was less active than NiIL-Zeoβ complexes, with activities above 1 s−1 with 100% selectivity for butenes (96% in 1-butene). NiIL-Al-MCM-41 system was more active than NiIL-MCM-41 system and showed an activity of 2.3 s−1 with 90% selectivity in 1-butenes." @default.
• W2800624871 created "2018-05-17" @default.
• W2800624871 creator A5002154345 @default.
• W2800624871 creator A5023761939 @default.
• W2800624871 creator A5054026298 @default.
• W2800624871 creator A5074141072 @default.
• W2800624871 date "2018-05-04" @default.
• W2800624871 modified "2023-10-17" @default.
• W2800624871 title "Nickel Complexes Immobilized in Modified Ionic Liquids Anchored in Structured Materials for Ethylene Oligomerization" @default.
• W2800624871 cites W1517920937 @default.
• W2800624871 cites W169553439 @default.
• W2800624871 cites W1978815693 @default.
• W2800624871 cites W1982540916 @default.
• W2800624871 cites W1982784029 @default.
• W2800624871 cites W1995783576 @default.
• W2800624871 cites W2001907233 @default.
• W2800624871 cites W2038041039 @default.
• W2800624871 cites W2041086094 @default.
• W2800624871 cites W2041638487 @default.
• W2800624871 cites W2046531333 @default.
• W2800624871 cites W2052859897 @default.
• W2800624871 cites W2065937208 @default.
• W2800624871 cites W2070644838 @default.
• W2800624871 cites W2070771614 @default.
• W2800624871 cites W2072371071 @default.
• W2800624871 cites W2074523257 @default.
• W2800624871 cites W2076634441 @default.
• W2800624871 cites W2080864025 @default.
• W2800624871 cites W2088967002 @default.
• W2800624871 cites W2091624295 @default.
• W2800624871 cites W2092150044 @default.
• W2800624871 cites W2092698520 @default.
• W2800624871 cites W2094730013 @default.
• W2800624871 cites W2095018307 @default.
• W2800624871 cites W2151277976 @default.
• W2800624871 cites W2168889700 @default.
• W2800624871 cites W2596962863 @default.
• W2800624871 cites W744527358 @default.
• W2800624871 doi "https://doi.org/10.3390/app8050717" @default.
• W2800624871 hasPublicationYear "2018" @default.
• W2800624871 type Work @default.
• W2800624871 sameAs 2800624871 @default.
• W2800624871 citedByCount "7" @default.
• W2800624871 countsByYear W28006248712019 @default.
• W2800624871 countsByYear W28006248712020 @default.
• W2800624871 countsByYear W28006248712021 @default.
• W2800624871 countsByYear W28006248712022 @default.
• W2800624871 crossrefType "journal-article" @default.
• W2800624871 hasAuthorship W2800624871A5002154345 @default.
• W2800624871 hasAuthorship W2800624871A5023761939 @default.
• W2800624871 hasAuthorship W2800624871A5054026298 @default.
• W2800624871 hasAuthorship W2800624871A5074141072 @default.
• W2800624871 hasBestOaLocation W28006248711 @default.
• W2800624871 hasConcept C118792377 @default.
• W2800624871 hasConcept C145148216 @default.
• W2800624871 hasConcept C150394285 @default.
• W2800624871 hasConcept C154881586 @default.
• W2800624871 hasConcept C161790260 @default.
• W2800624871 hasConcept C162711632 @default.
• W2800624871 hasConcept C178790620 @default.
• W2800624871 hasConcept C179104552 @default.
• W2800624871 hasConcept C185592680 @default.
• W2800624871 hasConcept C188027245 @default.
• W2800624871 hasConcept C2182769 @default.
• W2800624871 hasConcept C2776164856 @default.
• W2800624871 hasConcept C2777765387 @default.
• W2800624871 hasConcept C2778077586 @default.
• W2800624871 hasConcept C2778597550 @default.
• W2800624871 hasConcept C504270822 @default.
• W2800624871 hasConceptScore W2800624871C118792377 @default.
• W2800624871 hasConceptScore W2800624871C145148216 @default.
• W2800624871 hasConceptScore W2800624871C150394285 @default.
• W2800624871 hasConceptScore W2800624871C154881586 @default.
• W2800624871 hasConceptScore W2800624871C161790260 @default.
• W2800624871 hasConceptScore W2800624871C162711632 @default.
• W2800624871 hasConceptScore W2800624871C178790620 @default.
• W2800624871 hasConceptScore W2800624871C179104552 @default.
• W2800624871 hasConceptScore W2800624871C185592680 @default.
• W2800624871 hasConceptScore W2800624871C188027245 @default.
• W2800624871 hasConceptScore W2800624871C2182769 @default.
• W2800624871 hasConceptScore W2800624871C2776164856 @default.
• W2800624871 hasConceptScore W2800624871C2777765387 @default.
• W2800624871 hasConceptScore W2800624871C2778077586 @default.
• W2800624871 hasConceptScore W2800624871C2778597550 @default.
• W2800624871 hasConceptScore W2800624871C504270822 @default.
• W2800624871 hasIssue "5" @default.
• W2800624871 hasLocation W28006248711 @default.
• W2800624871 hasLocation W28006248712 @default.
• W2800624871 hasOpenAccess W2800624871 @default.
• W2800624871 hasPrimaryLocation W28006248711 @default.
• W2800624871 hasRelatedWork W1598915923 @default.
• W2800624871 hasRelatedWork W1659225723 @default.
• W2800624871 hasRelatedWork W2027123251 @default.
• W2800624871 hasRelatedWork W2034308726 @default.
• W2800624871 hasRelatedWork W2090801288 @default.
• W2800624871 hasRelatedWork W2278748475 @default.
• W2800624871 hasRelatedWork W2363304269 @default.
• W2800624871 hasRelatedWork W2383414774 @default.

• next