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• W2800661203 abstract "A novel and efficient method for the aminolysis of trizole epoxides is described. This method consists of a facile ring opening of the epoxides mediated by t-BuOMgCl generated in situ from amine hydrochlorides and (t-BuO)2Mg. The desired β-amino alcohols were obtained in good yields without employing other heavy metals or precious catalysts. The optimized conditions were successfully applied to the synthesis of a number of potential triazole antifungal compounds as well as efinaconazole on up to a 700 g scale." @default.
• W2800661203 created "2018-05-17" @default.
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• W2800661203 date "2018-04-26" @default.
• W2800661203 modified "2023-09-26" @default.
• W2800661203 title "A Facile Epoxide Aminolysis Promoted by (<i>t</i>-BuO)₂Mg and Its Application to the Synthesis of Efinaconazole" @default.
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• W2800661203 doi "https://doi.org/10.1021/acs.oprd.8b00081" @default.
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