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- W2800774792 abstract "The first catalytic enantioselective γ-boryl substitution of CF3 -substituted alkenes is reported. A series of CF3 -substituted alkenes was treated with a diboron reagent in the presence of a copper(I)/Josiphos catalyst to afford the corresponding optically active γ,γ-gem-difluoroallylboronates in high enantioselectivity. The thus obtained products could be readily converted into the corresponding difluoromethylene-containing homoallylic alcohols using highly stereospecific allylation reactions." @default.
- W2800774792 created "2018-05-17" @default.
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- W2800774792 date "2018-05-16" @default.
- W2800774792 modified "2023-10-17" @default.
- W2800774792 title "A Copper(I)-Catalyzed Enantioselective γ-Boryl Substitution of Trifluoromethyl-Substituted Alkenes: Synthesis of Enantioenriched γ,γ-<i>gem</i> -Difluoroallylboronates" @default.
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- W2800774792 doi "https://doi.org/10.1002/anie.201803663" @default.
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