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- W2800805544 abstract "The replacement of water by organic solvents in capillary electrophoretic (CE) techniques affects essentially all physicochemical properties of analytes and BGE components, and, in turn, all crucial operational parameters. A brief, yet comprehensive overview of the theoretical principles as well as relevant consequences of these solvent-induced changes are provided. Specifically, shifts in proton transfer equilibria (pKa values), impact on electrophoretic and electroosmotic mobility, occurrence of homo- and heteroassociation phenomena, and the combined consequences of organic solvents on the crucial figures of merits of electrophoretic separation, i.e., selectivity, efficiency, and resolution are addressed. Selected examples are provided in which the specific properties of organic solvents have been exploited for method development. This chapter will hopefully be useful for researchers interested in employing organic solvents in CE for specific problems, both for the interpretation of current results and for the rational design of future studies." @default.
- W2800805544 created "2018-05-17" @default.
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- W2800805544 date "2018-01-01" @default.
- W2800805544 modified "2023-10-16" @default.
- W2800805544 title "Capillary Electrophoresis in Organic Solvents" @default.
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- W2800805544 doi "https://doi.org/10.1016/b978-0-12-809375-7.00004-6" @default.
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