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• W2800806553 abstract "In the present work, mixture of melamine and isophthalaldehyde undergo simultaneous polymerization, carbonization, and in situ activation in the presence of molten salt media through a single all-in-one route to design microporous carbons with high specific surface areas (~3000 m2/g). The effect of the activation temperature and molten salts on the polymerization process and final texture of the carbon was explored. Carbon materials prepared at 700 °C, in the presence of KOH (referred as MIK-700), exhibited a narrower pore-size distribution ~1.05 nm than those prepared in the presence of the eutectic KOH-NaOH mixture (MIKN). Additionally, MIK-700 possesses an optimum micropore volume (1.33 cm3/g) along with a high nitrogen content (2.66 wt%), resulting in the excellent CO2 adsorption capacity of 9.7 mmol/g at 273 K and 1 bar. Similarly, the high specific area and highest total pore volume play an important role in H2 storage at 77 K, with 4.0 wt% uptake by MIKN-800 (specific surface area and pore volume of 2984 m2/g and 1.98 cm3/g, respectively.) Thus, the facile one-step solvent-free synthesis and activation strategy is an economically favorable avenue for designing microporous carbons as an efficient gas adsorbents." @default.
• W2800806553 created "2018-05-17" @default.
• W2800806553 creator A5080823003 @default.
• W2800806553 creator A5082212006 @default.
• W2800806553 date "2018-04-17" @default.
• W2800806553 modified "2023-10-12" @default.
• W2800806553 title "Microporous carbons derived from melamine and isophthalaldehyde: One-pot condensation and activation in a molten salt medium for efficient gas adsorption" @default.
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• W2800806553 doi "https://doi.org/10.1038/s41598-018-24308-z" @default.
• W2800806553 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5904172" @default.
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• W2800806553 hasPublicationYear "2018" @default.
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