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- W2800820669 abstract "This chapter summarizes key synthetic chemistries for metal alkyls. In manufacture of polyolefins, the most important metal alkyls are those of aluminum and magnesium. Aluminum alkyls and magnesium alkyls fulfill several roles in Ziegler–Natta (ZN) polymerization catalyst systems. The two most important are as raw materials for catalyst synthesis and as cocatalysts for the transition metal catalyst. Aluminum alkyls are used in large excess in ZN catalyst systems. In the early history of industrial ZN catalysts, diethylaluminum chloride (DEAC) and ethylaluminum sesquichloride (EASC) were the most important and functioned as both reducing agents and cocatalysts. They were readily available and relatively inexpensive and performed well with first-generation ZN catalysts. Impetus for using magnesium alkyls in ZN catalyst synthesis was provided by the discovery that magnesium salts, especially MgCl2, are excellent supports for ZN catalysts." @default.
- W2800820669 created "2018-05-17" @default.
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- W2800820669 date "2018-04-23" @default.
- W2800820669 modified "2023-10-12" @default.
- W2800820669 title "Industrial Metal Alkyls and Their Use in Polyolefin Catalysts" @default.
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- W2800820669 doi "https://doi.org/10.1002/9781119242277.ch1" @default.
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