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• W2800932016 abstract "Lithium alkoxide activates a monoorganosilane to generate a transient LiH/alkoxysilane complex, which quickly reacts with aryl and alkenyl halides at 25 °C to deliver a diorganosilane product. Experimental and theoretical studies suggest that the reaction includes nucleophilic attack of LiH on the halogen atom of the organic halide to generate a transient organolithium/alkoxysilane intermediate, which undergoes quick carbon-silicon bond formation within the complex." @default.
• W2800932016 created "2018-05-17" @default.
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• W2800932016 date "2018-05-01" @default.
• W2800932016 modified "2023-10-16" @default.
• W2800932016 title "Silylation of Aryl Halides with Monoorganosilanes Activated by Lithium Alkoxide" @default.
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• W2800932016 doi "https://doi.org/10.1021/acs.orglett.8b00818" @default.
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