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- W2801036747 abstract "Rational understanding of the structural features involving different noncovalent interactions is necessary to design a liquid crystal (LC) or an organogelator. Herein, we report the effect of the number and positions of alkoxy chains on the self-assembly induced physical properties of a few π-conjugated molecules. For this purpose, we designed and synthesized three C3-symmetrical molecules based on oligo(p-phenylenevinylene), C3OPV1–3. The self-assembly properties of these molecules are studied in the solid and solution states. All of the three molecules follow the isodesmic self-assembly pathway. Upon cooling from isotropic melt, C3OPV1 having nine alkoxy chains (−OC12H25) formed a columnar phase with two-dimensional rectangular lattice and retained the LC phase even at room temperature. Interestingly, when one of the −OC12H25 groups from each of the end benzene rings is knocked out, the resultant molecule, C3OPV2 lost the LC property, however, transformed as a gelator in toluene and n-decane. Surprisingly, when the −OC12H25 group from the middle position is removed, the resultant molecule C3OPV3 failed to form either the LC or the gel phases." @default.
- W2801036747 created "2018-05-17" @default.
- W2801036747 creator A5001394282 @default.
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- W2801036747 date "2018-04-20" @default.
- W2801036747 modified "2023-10-10" @default.
- W2801036747 title "Transforming a <i>C</i><sub>3</sub>-Symmetrical Liquid Crystal to a π-Gelator by Alkoxy Chain Variation" @default.
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- W2801036747 cites W1967065793 @default.
- W2801036747 cites W1969315280 @default.
- W2801036747 cites W1970783254 @default.
- W2801036747 cites W1975193982 @default.
- W2801036747 cites W1978067626 @default.
- W2801036747 cites W1982785372 @default.
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- W2801036747 doi "https://doi.org/10.1021/acsomega.8b00496" @default.
- W2801036747 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6641626" @default.
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