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- W2801055625 abstract "Abstract Three different series of half‐sandwich Os(II) complexes, namely [OsCl 2 ( η 6 ‐ p ‐cymene){PPh 2 (NR 2 )}] [R=Me ( 5a ), Et ( 5b )], [OsCl 2 ( η 6 ‐ p ‐cymene){PPh(NR 2 ) 2 }] [R=Me ( 6a ), Et ( 6b )] and [OsCl 2 ( η 6 ‐ p ‐cymene){P(NR 2 ) 3 }] [R=Me ( 7a ), Et ( 7b )], have been synthesized. These species proved to be catalytically active for the selective hydration of organonitriles, with compound [OsCl 2 ( η 6 ‐ p ‐cymene){PPh 2 (NMe 2 )}] ( 5a ) being the most effective. In addition, the catalytic activity of 5a was found to be superior to those shown by related Ru(II), Ru(IV), Rh(I) and Pt(II) species containing the amino‐phosphane PPh 2 (NMe 2 ), i. e. compounds [RuCl 2 ( η 6 ‐ p ‐cymene){PPh 2 (NMe 2 )}] ( 10 ), [RuCl 2 ( η 3 : η 3 ‐C 10 H 16 ){PPh 2 (NMe 2 )}] ( 12 ), [RhCl(COD){PPh 2 (NMe 2 )}] ( 13 ) and cis ‐[PtCl 2 {PPh 2 (NMe 2 )} 2 ] ( 15 ). Details on the synthesis and characterization of complexes 10 , 12 and 15 are also included, along with a discussion on the role played by the ligand PPh 2 (NMe 2 ) during the catalytic reactions. In this sense, the amino‐phosphane does not act as H‐bond acceptor for the water molecule, generating instead in the aqueous reaction medium the cooperative phosphinous acid ligand PPh 2 (OH)." @default.
- W2801055625 created "2018-05-17" @default.
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- W2801055625 date "2018-04-24" @default.
- W2801055625 modified "2023-09-27" @default.
- W2801055625 title "Cymene-Osmium(II) Complexes with Amino-Phosphane Ligands as Precatalysts for Nitrile Hydration Reactions" @default.
- W2801055625 cites W140367106 @default.
- W2801055625 cites W1495102840 @default.
- W2801055625 cites W1551836447 @default.
- W2801055625 cites W1836258527 @default.
- W2801055625 cites W1943180441 @default.
- W2801055625 cites W1966658852 @default.
- W2801055625 cites W1967078335 @default.
- W2801055625 cites W1970788163 @default.
- W2801055625 cites W1971830835 @default.
- W2801055625 cites W1977639310 @default.
- W2801055625 cites W1984017956 @default.
- W2801055625 cites W1985597923 @default.
- W2801055625 cites W1988949760 @default.
- W2801055625 cites W1989646612 @default.
- W2801055625 cites W1990496264 @default.
- W2801055625 cites W1993398574 @default.
- W2801055625 cites W1993959006 @default.
- W2801055625 cites W2001379731 @default.
- W2801055625 cites W2007843911 @default.
- W2801055625 cites W2021751308 @default.
- W2801055625 cites W2023551209 @default.
- W2801055625 cites W2023721627 @default.
- W2801055625 cites W2026293914 @default.
- W2801055625 cites W2030847400 @default.
- W2801055625 cites W2031734182 @default.
- W2801055625 cites W2033957033 @default.
- W2801055625 cites W2046981219 @default.
- W2801055625 cites W2052342356 @default.
- W2801055625 cites W2055034206 @default.
- W2801055625 cites W2055392196 @default.
- W2801055625 cites W2060936548 @default.
- W2801055625 cites W2062400798 @default.
- W2801055625 cites W2064890031 @default.
- W2801055625 cites W2065998871 @default.
- W2801055625 cites W2076021819 @default.
- W2801055625 cites W2076982282 @default.
- W2801055625 cites W2080440758 @default.
- W2801055625 cites W2084281798 @default.
- W2801055625 cites W2086416706 @default.
- W2801055625 cites W2101381885 @default.
- W2801055625 cites W2110631566 @default.
- W2801055625 cites W2110998250 @default.
- W2801055625 cites W2116992852 @default.
- W2801055625 cites W2118948052 @default.
- W2801055625 cites W2131727850 @default.
- W2801055625 cites W2146820308 @default.
- W2801055625 cites W2156962454 @default.
- W2801055625 cites W2157574023 @default.
- W2801055625 cites W2159608254 @default.
- W2801055625 cites W2165418355 @default.
- W2801055625 cites W2265997152 @default.
- W2801055625 cites W2315429615 @default.
- W2801055625 cites W2317292993 @default.
- W2801055625 cites W2326467555 @default.
- W2801055625 cites W2327387655 @default.
- W2801055625 cites W2327835775 @default.
- W2801055625 cites W2327968277 @default.
- W2801055625 cites W2331489161 @default.
- W2801055625 cites W2333005737 @default.
- W2801055625 cites W2334477814 @default.
- W2801055625 cites W2378282695 @default.
- W2801055625 cites W2492070627 @default.
- W2801055625 cites W2523045592 @default.
- W2801055625 cites W2559048901 @default.
- W2801055625 cites W2588299531 @default.
- W2801055625 cites W2604164152 @default.
- W2801055625 cites W2746844097 @default.
- W2801055625 cites W2786454134 @default.
- W2801055625 cites W2949147310 @default.
- W2801055625 cites W2949360879 @default.
- W2801055625 cites W2950258820 @default.
- W2801055625 cites W2950406612 @default.
- W2801055625 cites W2950450213 @default.
- W2801055625 cites W2950563028 @default.
- W2801055625 cites W4234892163 @default.
- W2801055625 doi "https://doi.org/10.1002/slct.201801023" @default.
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