Matches in SemOpenAlex for { <https://semopenalex.org/work/W2801154889> ?p ?o ?g. }
- W2801154889 endingPage "1500" @default.
- W2801154889 startingPage "1493" @default.
- W2801154889 abstract "We have probed for reaction intermediates involved in the dual-gold-catalyzed activation of a conjugated 1,5-diyne substrate and its further coupling to benzene in the liquid phase. This was done by sampling the reaction mixture by electrospray ionization followed by high-resolution ion mobility mass spectrometry—under conditions allowing for the resolution of structural isomers differing in their collision cross sections by less than 0.5%. For the cationic mass corresponding to catalyst + diyne (activation stage) we resolve four isomers. At the mass corresponding to catalyst + diyne + benzene, two isomers are observed. By comparing the experimentally obtained cross sections to those inferred for model structures derived from density functional computations, we find our measurements to be consistent with the proposed solution mechanism. This constitutes the first direct observation of intermediates in dual gold catalysis and supports the previous inference that the mechanism involves cooperative interactions between two gold centers." @default.
- W2801154889 created "2018-05-17" @default.
- W2801154889 creator A5001473159 @default.
- W2801154889 creator A5004498912 @default.
- W2801154889 creator A5004781839 @default.
- W2801154889 creator A5012455703 @default.
- W2801154889 creator A5024817523 @default.
- W2801154889 creator A5034392272 @default.
- W2801154889 creator A5035175627 @default.
- W2801154889 creator A5057346916 @default.
- W2801154889 creator A5067884400 @default.
- W2801154889 creator A5072433794 @default.
- W2801154889 creator A5073334841 @default.
- W2801154889 creator A5082660259 @default.
- W2801154889 creator A5084714835 @default.
- W2801154889 date "2018-05-04" @default.
- W2801154889 modified "2023-10-15" @default.
- W2801154889 title "Detection of Intermediates in Dual Gold Catalysis Using High-Resolution Ion Mobility Mass Spectrometry" @default.
- W2801154889 cites W134337122 @default.
- W2801154889 cites W1973133876 @default.
- W2801154889 cites W1975785335 @default.
- W2801154889 cites W1979497806 @default.
- W2801154889 cites W1983172097 @default.
- W2801154889 cites W1984471932 @default.
- W2801154889 cites W2010741465 @default.
- W2801154889 cites W2012023524 @default.
- W2801154889 cites W2017857396 @default.
- W2801154889 cites W2033076450 @default.
- W2801154889 cites W2034666141 @default.
- W2801154889 cites W2037964091 @default.
- W2801154889 cites W2046199828 @default.
- W2801154889 cites W2054378949 @default.
- W2801154889 cites W2060865127 @default.
- W2801154889 cites W2068067410 @default.
- W2801154889 cites W2069006374 @default.
- W2801154889 cites W2071772558 @default.
- W2801154889 cites W2080140933 @default.
- W2801154889 cites W2095100262 @default.
- W2801154889 cites W2099674459 @default.
- W2801154889 cites W2102987254 @default.
- W2801154889 cites W2107250741 @default.
- W2801154889 cites W2109314832 @default.
- W2801154889 cites W2121970136 @default.
- W2801154889 cites W2122235410 @default.
- W2801154889 cites W2127031980 @default.
- W2801154889 cites W2128147343 @default.
- W2801154889 cites W2140353287 @default.
- W2801154889 cites W2141379893 @default.
- W2801154889 cites W2143981217 @default.
- W2801154889 cites W2147484143 @default.
- W2801154889 cites W2154604185 @default.
- W2801154889 cites W2160574842 @default.
- W2801154889 cites W2170989990 @default.
- W2801154889 cites W2214705350 @default.
- W2801154889 cites W2280587714 @default.
- W2801154889 cites W2313647165 @default.
- W2801154889 cites W2315509366 @default.
- W2801154889 cites W2316055668 @default.
- W2801154889 cites W2325016811 @default.
- W2801154889 cites W2330424590 @default.
- W2801154889 cites W2344219184 @default.
- W2801154889 cites W2398615568 @default.
- W2801154889 cites W2465888590 @default.
- W2801154889 cites W2516176679 @default.
- W2801154889 cites W2524591963 @default.
- W2801154889 cites W2582021251 @default.
- W2801154889 cites W2611761348 @default.
- W2801154889 cites W2617562274 @default.
- W2801154889 cites W2624205200 @default.
- W2801154889 cites W2756225406 @default.
- W2801154889 cites W2762183110 @default.
- W2801154889 cites W2766662133 @default.
- W2801154889 cites W2949680609 @default.
- W2801154889 cites W2950024730 @default.
- W2801154889 cites W2950265756 @default.
- W2801154889 cites W2951578410 @default.
- W2801154889 cites W2952082074 @default.
- W2801154889 cites W4211044815 @default.
- W2801154889 doi "https://doi.org/10.1021/acs.organomet.8b00128" @default.
- W2801154889 hasPublicationYear "2018" @default.
- W2801154889 type Work @default.
- W2801154889 sameAs 2801154889 @default.
- W2801154889 citedByCount "28" @default.
- W2801154889 countsByYear W28011548892018 @default.
- W2801154889 countsByYear W28011548892019 @default.
- W2801154889 countsByYear W28011548892020 @default.
- W2801154889 countsByYear W28011548892021 @default.
- W2801154889 countsByYear W28011548892022 @default.
- W2801154889 countsByYear W28011548892023 @default.
- W2801154889 crossrefType "journal-article" @default.
- W2801154889 hasAuthorship W2801154889A5001473159 @default.
- W2801154889 hasAuthorship W2801154889A5004498912 @default.
- W2801154889 hasAuthorship W2801154889A5004781839 @default.
- W2801154889 hasAuthorship W2801154889A5012455703 @default.
- W2801154889 hasAuthorship W2801154889A5024817523 @default.
- W2801154889 hasAuthorship W2801154889A5034392272 @default.
- W2801154889 hasAuthorship W2801154889A5035175627 @default.
- W2801154889 hasAuthorship W2801154889A5057346916 @default.