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- W2801251015 abstract "Abstract Diarylamine‐fused subporphyrins 1 a and 1 b were synthesized from β,β‐diiodo‐ meso ‐chloro subporphyrin 2 through a one‐pot procedure involving nucleophilic aromatic substitution and S RN 1‐type intramolecular fusion reaction as the first example of meso ‐nitrogen‐embedded subporphyrin. While non‐fused counterparts 3 b and 4 b display effective fluorescence quenching due to twisted intramolecular charge transfer (TICT) in CH 2 Cl 2 at room temperature, 1 b emits fluorescence with Φ F =0.18 under the same conditions, because conformational twisting is not allowed due to the fused structure. In addition, the oxidative titration with tris(4‐bromophenyl)ammoniumyl hexachloroantimonate gave cation radical 7 for 1 a and cation radical and dication for 1 b . Actually, cation radical 7 was isolated through separation over silica gel column but was found to slowly decompose in concentrated solutions." @default.
- W2801251015 created "2018-05-17" @default.
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- W2801251015 date "2018-05-15" @default.
- W2801251015 modified "2023-10-11" @default.
- W2801251015 title "Diarylamine‐Fused Subporphyrins: Proof of Twisted Intramolecular Charge Transfer (TICT) Mechanism" @default.
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- W2801251015 doi "https://doi.org/10.1002/chem.201801576" @default.
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