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• W2801274429 abstract "Abstract There is a growing demand for nanoparticles coated with graphene due their promise in various applications such as batteries and supercapacitors, sorbents, and biomedical applications. A good example is Si where its combination with carbon is considered important for electronics and energy applications, such as lithium ion batteries, polymer based composites and even bio-medical applications. In this study, we aim to develop a very simple chemical vapor deposition approach to form graphitized Si nanoparticles in which ethanol serves as the C feedstock. This differs from other CVD approaches which tend to use a gaseous hydrocarbon (e.g. CH 4 ) as the carbon feedstock. The use of ethanol in which Ar is simply bubbled through liquid ethanol leads to a simpler and cheaper approach. Moreover, in conventional CVD, often an oxidant (e.g. CO 2 ) is added to aid graphitization and minimize the formation of SiC at the Si surface. Ethanol provides a source of O which serves as an inbuilt oxidizer to aid graphitization and limit the formation of SiC. The simple synthesis approach allows one to tailor the number of graphene layers coating the Si nanoparticles through the three main synthesis parameters of ethanol supply, temperature and reaction time. Moreover, using ethanol as the precursor, lower graphitization temperatures than for methane can be used." @default.
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• W2801274429 date "2018-10-01" @default.
• W2801274429 modified "2023-10-16" @default.
• W2801274429 title "Facile graphitization of silicon nano-particles with ethanol based chemical vapor deposition" @default.
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• W2801274429 doi "https://doi.org/10.1016/j.nanoso.2018.04.001" @default.
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