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- W2801363008 abstract "The scalable preparation and functionalization of two-dimensional (2D) boron nitride (BN) are crucial for its practical applications. Herein, hydroxyl-functionalized BN (OBN) nanoplatelets have been successfully synthesized through a novel two-step method, involving a simple ball milling of bulk BN powders in the assistance of sodium hydroxide, which combine the synergetic effect of mechanical shear forces and chemical peeling, followed by annealing under air condition. The obtained OBN nanoplatelets result in high solubility and form stable dispersions in water or various organic solvents that can be utilized for multiple applications. Then, OBN nanoplatelet was used as platform for embedding supermolecular aggregate (DPCS) via ionic bonding and electrostatic interaction between dicyandiamide and multivalent anions phytic acid connected with cobalt ions (denoted as [email protected]). It is noted that introducing well-characterized [email protected] nanohybrids significantly improve the flame retardancy of epoxy acrylate (EA), i.e., 42.7% and 48.3% reductions in peak heat release rate and total heat release, respectively. In the case of EA/[email protected] system, the storage modulus at 25 °C was dramatically improved by 80.7%, and glass transition temperature was shifted to higher value; the friction coefficient value of EA/[email protected] composite sharp decline to 0.077, which can be belong to the “superlubrication” phenomena. The excellent properties of these EA composites result from synergetic coupled effect between DPCS supermolecular and BN ultrathin nanoplatelets, as well as good interface interaction between [email protected] and EA matrix." @default.
- W2801363008 created "2018-05-17" @default.
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- W2801363008 date "2018-10-01" @default.
- W2801363008 modified "2023-10-12" @default.
- W2801363008 title "Self-assembled supermolecular aggregate supported on boron nitride nanoplatelets for flame retardant and friction application" @default.
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- W2801363008 doi "https://doi.org/10.1016/j.cej.2018.05.053" @default.
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