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- W2801474414 abstract "Spherical nanoparticles of ZrO2 with 2 and 10 mol% EuO1.5 up to 20 nm size were prepared by the method of hydrothermal synthesis for luminescent functionalization of the polymer-inorganic nanocomposites based on poly(methyl methacrylate). Surface modification of oxide nanoparticles was carried out by 3-(trimethoxysilyl)propyl methacrylate, dimethoxymethylvinyl silane and 2-hydroxyethyl methacrylate to provide uniform distribution and to prevent agglomeration of nanosized filler in the polymer matrix. Polymer-inorganic composites were synthesized by in situ free radical polymerization in bulk. Structuring of ZrO2 -EuO1.5 nanoparticles in the poly(methyl methacrylate) was studied by very-small-angle neutron scattering. According to the results, the dependence of photoluminescent properties of ZrO2 -EuO1.5 nanoparticles on the content of lanthanide, the symmetry of the crystal field, surface treatment and the polymer matrix were established. A correlation was shown between Stark splitting in luminescence spectra of ZrO2 -EuO1.5 nanoparticles and their phase composition. Using MMT-assay it was shown that composites based on poly(methyl methacrylate) and ZrO2 -EuO1.5 nanoparticles do not have cytotoxic properties, which makes it possible to use them as prosthesis materials with contrasted and luminescent imaging properties." @default.
- W2801474414 created "2018-05-17" @default.
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- W2801474414 date "2018-04-23" @default.
- W2801474414 modified "2023-09-26" @default.
- W2801474414 title "Luminescence of Eu<sup>3+</sup> ions in hybrid polymer-inorganic composites based on poly(methyl methacrylate) and zirconia nanoparticles" @default.
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- W2801474414 doi "https://doi.org/10.1002/bio.3476" @default.
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- W2801474414 hasPublicationYear "2018" @default.
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