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- W2801490087 abstract "Here, we report separately enhanced dual emissions of the amphiphilic derivative of 2-(2'-hydroxyphenyl)benzothiazole (denoted as HBT-11) by supramolecular complexation with cyclodextrins (CDs). When dispersed in water, HBT-11 shows two relatively weak emission bands, which can be assigned to the emissions of enol- and keto-forms, the two tautomers, owing to excited-state intramolecular proton transfers. Upon the addition of α-CD and β-CD, the keto- and enol-emissions, respectively, are separately enhanced; the enhancement effect is due to the formation of HBT-11/α-CD and HBT-11/β-CD complexes through multiple hydrogen bonding and host-guest interactions, respectively. It is worth to note that the keto-emission caused by the complex of HBT-11/α-CD has a much shorter wavelength compared with that of the aggregates formed by pure HBT-11. To the best of our knowledge, this is the first time that a study on keto-emission of the isolated HBT chromophore has been reported." @default.
- W2801490087 created "2018-05-17" @default.
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- W2801490087 date "2018-05-30" @default.
- W2801490087 modified "2023-09-29" @default.
- W2801490087 title "Separately enhanced dual emissions of the amphiphilic derivative of 2-(2'-hydroxylphenyl) benzothiazole by supramolecular complexation." @default.
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- W2801490087 doi "https://doi.org/10.1039/c8sm00552d" @default.
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