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• W2801547568 abstract "CO2 hydrogenation is a potential alternative to conventional petrochemical methods for making commodity chemicals and fuels. Research in this area has focused mostly on transition-metal-based catalysts. Here we show that hydrated alkali carbonates promote CO2 hydrogenation to formate, oxalate, and other C2+ carboxylates at elevated temperature and pressure in the absence of transition-metal catalysts or solvent. The reactions proceed rapidly, reaching up to 56% yield (with respect to CO32-) within minutes. Isotope labeling experiments indicate facile H2 and C-H deprotonations in the alkali cation-rich reaction media and identify probable intermediates for the C-C bond formations leading to the various C2+ products. The carboxylate salts are in equilibrium with volatile carboxylic acids under CO2 hydrogenation conditions, which may enable catalytic carboxylic acid syntheses. Our results provide a foundation for base-promoted and base-catalyzed CO2 hydrogenation processes that could complement existing approaches." @default.
• W2801547568 created "2018-05-17" @default.
• W2801547568 creator A5022011713 @default.
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• W2801547568 date "2018-04-30" @default.
• W2801547568 modified "2023-10-12" @default.
• W2801547568 title "Carbonate-Promoted Hydrogenation of Carbon Dioxide to Multicarbon Carboxylates" @default.
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• W2801547568 doi "https://doi.org/10.1021/acscentsci.8b00108" @default.
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