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• W2801555127 abstract "Transmetallation of Pb(OAc)4 with R2 Hg (1), followed by treatment with HCl in Et2 O, provided RPbCl3 (2), the first kinetically stabilized monoorganolead trihalide that resists reductive elimination under ambient conditions. The kinetic stabilisation relies on an intramolecularly coordinating O-donor substituent (R=6-Ph2 P(O)-Ace-5-). The gram-scale preparation of 2 was key for the synthesis of unsymmetrically substituted diaryllead dichlorides RR'PbCl2 (3 a, R'=Ph; 3 b, R'=4-MeOC6 H4 ; 3 c, R'=4-Me2 NC6 H4 )." @default.
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• W2801555127 date "2018-04-14" @default.
• W2801555127 modified "2023-10-16" @default.
• W2801555127 title "A Monoaryllead Trichloride That Resists Reductive Elimination" @default.
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• W2801555127 doi "https://doi.org/10.1002/anie.201712944" @default.
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