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• W2801591164 abstract "The evaporation of a dicationic ionic liquid, 1,3-bis(3-methylimidazolium-1-yl)propane bis(trifluoromethanesulfonyl)amide ([C3(MIm)22+][Tf2N–]2), was studied by Knudsen effusion mass spectrometry. Its evaporation is accompanied by a partial thermal decomposition producing monocationic ionic liquids, 1,3-dimethylimidazolium and 1-(2-propenyl)-3-methylimidazolium bis(trifluoromethanesulfonyl)amides, as volatile products. This decomposition does not affect the vaporization characteristics of [C3(MIm)22+][Tf2N–]2, which were established to be as follows. The vaporization enthalpy (550 K) is equal to (155.5 ± 3.2) kJ·mol–1; the saturated vapor pressure is described by the equation ln(p/Pa) = −(18699 ± 381)/(T/K) + (30.21 ± 0.82) in the range of 508–583 K. 1,3-Bis(3-methylimidazolium-1-yl)propane bis(trifluoromethanesulfonyl)amide is the first dicationic ionic liquid, the vaporization characteristics of which were determined with an acceptable accuracy." @default.
• W2801591164 created "2018-05-17" @default.
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• W2801591164 date "2018-04-23" @default.
• W2801591164 modified "2023-10-02" @default.
• W2801591164 title "Evaporation Study of an Ionic Liquid with a Double-Charged Cation" @default.
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• W2801591164 doi "https://doi.org/10.1021/acs.jpca.8b02488" @default.
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• W2801591164 hasPublicationYear "2018" @default.
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