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• W2801604517 abstract "Abstract Herein we report general methods allowing the synthesis of various perfluoroalkylated corannulenes with a specific substitution pattern. Variable temperature NMR spectroscopic investigations revealed dynamic behavior which was analyzed by line shape analysis. The activation parameters of these dynamic processes were determined. For a tetrasubstituted compound it was possible to observe through space scalar coupling. The packing motifs were elucidated by X‐ray crystallography, showing that the substitution pattern as well as the size of substituents strongly influence intermolecular π‐stacking. The reduction potentials of the perfluoroalkylated compounds were determined by cyclic voltammetry." @default.
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• W2801604517 date "2018-06-27" @default.
• W2801604517 modified "2023-09-25" @default.
• W2801604517 title "Selective Synthesis of Perfluoroalkylated Corannulenes and Investigation of their Structural, Dynamic and Electrochemical Behavior" @default.
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• W2801604517 doi "https://doi.org/10.1002/chem.201801021" @default.
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