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- W2801643578 abstract "Abstract The dependences of phase transition and luminescence properties upon both Eu 3+ concentration and heating temperature in air were investigated for GdTiNbO 6 :Eu 3+ fine crystals formed hydrothermally at 240 °C as aeschynite-type Eu x Gd 1-x TiNbO 6 solid solution. The as-prepared aeschynite solid solution in the concentration range x ≥ 0.70 did not show the phase transformation from an aeschynite- to an euxenite-type structure caused by heating at 1300 °C for 1 h in air. The present study suggested that the phase boundary between the aeschynite- and euxenite-type RETiNbO 6 in the EuTiNbO 6 -GdTiNbO 6 system, where RE was a rare earth, lay in the average RE 3+ ionic radius 0.1061 nm. The intense emissions attributed to the 5 D 0 → 7 F 1 and 5 D 0 → 7 F 2 transitions of Eu 3+ for the as-prepared samples were more improved by heating at 1100–1300°C in air. The material doped with 30 mol% Eu 3+ was preferred for UV-B excitation, in contrast, the material with 50 mol% Eu 3+ was preferred for visible light excitation." @default.
- W2801643578 created "2018-05-17" @default.
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- W2801643578 date "2018-09-01" @default.
- W2801643578 modified "2023-09-24" @default.
- W2801643578 title "Phase transition and luminescence properties of GdTiNbO6:Eu3+ formed by hydrothermal route" @default.
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- W2801643578 doi "https://doi.org/10.1016/j.materresbull.2018.04.029" @default.
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