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• W2801657142 startingPage "9773" @default.
• W2801657142 abstract "This work reports the total syntheses of Isodon diterpenes trichorabdal A and maoecrystal Z via a common bicyclo[3.2.1]octane intermediate, which chemically bridges the two distinct structures through a retro-aldol/aldol reaction cascade. Other synthetic features include an efficient cross-ring radical cyclization for rapid construction of an all carbon quaternary center commonly seen in Isodon diterpenoids, a challenging Ueno-Stork cyclization on to a sensitive 1,6-enone system, as well as a serial of chemoselective functional group manipulations in complex chemical environments." @default.
• W2801657142 created "2018-05-17" @default.
• W2801657142 creator A5049662554 @default.
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• W2801657142 date "2018-06-08" @default.
• W2801657142 modified "2023-10-17" @default.
• W2801657142 title "Total Syntheses of Trichorabdal A and Maoecrystal Z" @default.
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• W2801657142 doi "https://doi.org/10.1002/chem.201802083" @default.
• W2801657142 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29702738" @default.
• W2801657142 hasPublicationYear "2018" @default.
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