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- W2801679447 abstract "The copper-assisted radical carbofluorination of unactivated alkenes with fluoride ions is described. With [Cu(L3)F2]H2O (L3 = 4,4'-di(methoxycarbonyl)-2,2'-bipyridine) as the fluorine source and [Ag(DMPhen)(MeCN)]BF4 (DMPhen = 2,9-dimethyl-1,10-phenanthroline) as the chloride scavenger, the reaction of unactivated alkenes with CCl4 in acetonitrile provided the corresponding carbofluorination products in satisfactory yields. The protocol exhibited a wide functional group compatibility and broad substrate scope and could be extended to the use of a variety of activated alkyl chlorides other than CCl4. A copper-catalyzed fluorotrifluoromethylation of unactivated alkenes was then successfully developed with CsF as the fluorine source and Umemoto's reagent as the trifluoromethylating agent. A mechanism involving the fluorine atom transfer from Cu(II)-F complexes to alkyl radicals is proposed." @default.
- W2801679447 created "2018-05-17" @default.
- W2801679447 creator A5003114193 @default.
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- W2801679447 date "2018-04-25" @default.
- W2801679447 modified "2023-10-16" @default.
- W2801679447 title "Radical Carbofluorination of Unactivated Alkenes with Fluoride Ions" @default.
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- W2801679447 cites W1985562778 @default.
- W2801679447 cites W1986269250 @default.
- W2801679447 cites W1993507339 @default.
- W2801679447 cites W1993828969 @default.
- W2801679447 cites W1995679158 @default.
- W2801679447 cites W1998040938 @default.
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- W2801679447 cites W2008186722 @default.
- W2801679447 cites W2022926795 @default.
- W2801679447 cites W2027085486 @default.
- W2801679447 cites W2031214073 @default.
- W2801679447 cites W2031317139 @default.
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- W2801679447 cites W2153906089 @default.
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- W2801679447 doi "https://doi.org/10.1021/jacs.8b03077" @default.
- W2801679447 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29694036" @default.
- W2801679447 hasPublicationYear "2018" @default.
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