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- W2801709586 abstract "Currently, developing high voltage (beyond 2 V) rechargeable Mg-ion batteries still remains a great challenge owing to the limit of corrosive electrolyte and low compatibility of anode material. Here we report a facile one step solid state alloying route to synthesize nanoclustered Mg3Bi2 alloy as a high-performance anode to build up a 2 V Mg-ion battery using noncorrosive electrolyte. The fabricated nanoclustered Mg3Bi2 anode delivers a high reversible specific capacity (360 mAh g-1) with excellent stability (90.7% capacity retention over 200 cycles) and high Coulombic efficiency (average 98%) at 0.1 A g-1. The good performance is attributed to the stable nanostructures, which effectively accommodate the reversible Mg2+ ion insertion/deinsertion without losing electric contact among clusters. Significantly, the nanoclustered Mg3Bi2 anode can be coupled with high voltage cathode Prussian Blue to assemble a full cell using noncorrosive electrolyte, showing a stable cycling (88% capacity retention over 200 cycles at 0.2 A g-1) and good rate capability (103 mAh g-1 at 0.1 A g-1 and 58 mAh g-1 at 2 A g-1). The energy and power density of the as-fabricated full cell can reach up to 81 Wh kg-1 and 2850 W kg-1, respectively, which are both the highest values among the reported Mg-ion batteries using noncorrosive electrolytes. This study demonstrates a cost-effective route to fabricate stable and high voltage rechargeable Mg-ion battery potentially for grid-scale energy storage." @default.
- W2801709586 created "2018-05-17" @default.
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- W2801709586 date "2018-04-27" @default.
- W2801709586 modified "2023-10-16" @default.
- W2801709586 title "High Voltage Magnesium-ion Battery Enabled by Nanocluster Mg<sub>3</sub>Bi<sub>2</sub> Alloy Anode in Noncorrosive Electrolyte" @default.
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- W2801709586 doi "https://doi.org/10.1021/acsnano.8b01847" @default.
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- W2801709586 hasPublicationYear "2018" @default.
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