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- W2801806835 endingPage "5525" @default.
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- W2801806835 abstract "The palladium-catalyzed asymmetric decarboxylative allylic alkylation of trifluoromethoxy allyl enol carbonates afforded enantioenriched α-trifluoromethoxy allyl ketones that feature a tetrasubstituted α-stereogenic center in excellent yield and high enantioselectivity. The method was further extended to the asymmetric synthesis of α-difluoromethoxy and α-methoxy allyl ketones, which proceeded under similar catalytic conditions." @default.
- W2801806835 created "2018-05-17" @default.
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- W2801806835 date "2018-01-01" @default.
- W2801806835 modified "2023-10-18" @default.
- W2801806835 title "Asymmetric synthesis of α-trifluoromethoxy ketones with a tetrasubstituted α-stereogenic centre <i>via</i> the palladium-catalyzed decarboxylative allylic alkylation of allyl enol carbonates" @default.
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- W2801806835 doi "https://doi.org/10.1039/c8cc03131b" @default.
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