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• W2801810922 endingPage "8993" @default.
• W2801810922 startingPage "8989" @default.
• W2801810922 abstract "The replacement of noble metals by earth abundant metals is a desirable aim in catalysis and a possible way of conserving rare elements. The replacement is especially attractive if novel selectivity patterns are observed permitting the development of novel coupling reactions. Herein, we report on a novel, robust and reusable iron catalyst, which permits the selective hydrogenation of nitroarenes in the presence of hydrogenation-sensitive functional groups. Based on the selectivity pattern observed, the direct iron-catalyzed synthesis of imines and benzimidazoles from nitroarenes and aldehydes becomes feasible. In addition, we introduce the direct synthesis of quinoxalines from nitroarenes and diketones applying our catalyst." @default.
• W2801810922 created "2018-05-17" @default.
• W2801810922 creator A5055744658 @default.
• W2801810922 creator A5061603797 @default.
• W2801810922 date "2018-05-25" @default.
• W2801810922 modified "2023-09-24" @default.
• W2801810922 title "The Direct Synthesis of Imines, Benzimidazoles and Quinoxalines from Nitroarenes and Carbonyl Compounds by Selective Nitroarene Hydrogenation Employing a Reusable Iron Catalyst" @default.
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• W2801810922 doi "https://doi.org/10.1002/chem.201801525" @default.
• W2801810922 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29668069" @default.
• W2801810922 hasPublicationYear "2018" @default.
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