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- W2801974294 abstract "The excess Gibbs free energy-equation of state (GEEoS) models is presented based on the Peng-Robinson (PR) EoS combined with the Wong-Sandler (WS) mixing rule and the modified UNIFAC group contribution method (PR-WS-MUNIFAC). The average absolute deviation (AAD) of vapor phase mass fraction and the absolute average relative deviation (AARD) of pressure are 0.0047 and 0.53%, respectively, for R152a + R1234yf; 0.0064、0.0050 and 1.59%, respectively, for R32 + R125 + R134a. The VLE properties of the ternary mixture R1234yf + R290 + R134a as a drop-in replacement for R134a were predicted over the temperature range of (253.15–313.15 K) at 10 K intervals. The vapor–liquid-liquid equilibrium (VLLE) was qualitatively analyzed in theory, and the relevant phase equilibrium diagrams were constructed. The R290 + R134a system has clear characteristics of VLLE near the azeotropic point; the pressure of the upper critical end point (UCEP) is approximately 1.627 MPa. Liquid phase separation also exists in the ternary system of R1234yf + R290 + R134a." @default.
- W2801974294 created "2018-05-17" @default.
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- W2801974294 date "2018-09-01" @default.
- W2801974294 modified "2023-10-15" @default.
- W2801974294 title "Thermodynamic modeling of VLE and VLLE for the ternary system of 2,3,3,3-tetrafluoroprop-1-ene(R1234yf) + propane (R290) + 1,1,1,2-tetrafluoroethane(R134a) at 253.15 K-313.15 K" @default.
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- W2801974294 doi "https://doi.org/10.1016/j.ces.2018.04.052" @default.
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