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- W2801984724 abstract "Nanoscale zerovalent iron (nZVI) has been proposed to remediate heavy metal ions in the subsurface. However, the fate of metal-nZVI hybrid has not been fully investigated. In this study, we investigated (1) the long-term removal performance of nZVI for molybdate (Mo(VI)); (2) the relationship between the ageing of Mo-nZVI hybrid in specific solution chemistries and the remobilization of Mo(VI) from the hybrid; and (3) the effects of Mo-nZVI hybrid on cyanobacteria (Microcystis aeruginosa). Results showed that although common ions have limited influence on the removal ratio of Mo(VI) by nZVI, they do impact the structure evolution and transformation of the Mo-nZVI nanohybrid formed thereafter. Ageing time was crucial for the chemical stabilization of Mo-nZVI hybrid, but common groundwater ions retarded the stabilizing process, which may lead to a significant remobilization of Mo(VI) from the hybrid after exposure to water bodies. While low levels of Mo(VI) ions could stimulate the growth of M. aeruginosa, aged Mo-nZVI hybrid inhibited the growth of M. aeruginosa, except when ageing occurred in the presence of HPO42−/CO32− (which also retarded hybrid stabilization). This study shows that nZVI can immobilize Mo(VI) ions in groundwater, and the derived metal-nZVI hybrid can effectively suppress the potential growth of M. aeruginosa in river water." @default.
- W2801984724 created "2018-05-17" @default.
- W2801984724 creator A5039178317 @default.
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- W2801984724 creator A5081714493 @default.
- W2801984724 creator A5084961529 @default.
- W2801984724 date "2018-09-01" @default.
- W2801984724 modified "2023-09-29" @default.
- W2801984724 title "Impact of ageing on the fate of molybdate-zerovalent iron nanohybrid and its subsequent effect on cyanobacteria (Microcystis aeruginosa) growth in aqueous media" @default.
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- W2801984724 doi "https://doi.org/10.1016/j.watres.2018.04.037" @default.
- W2801984724 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29704758" @default.
- W2801984724 hasPublicationYear "2018" @default.
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