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- W2802012809 abstract "Abstract Organocatalytic synthesis of bi‐ and tricyclic fused 1,2,4‐oxadiazolines is reported. The reaction proceeds through oxidative cyclization of the corresponding amidoxime using 2,4,6‐tris(4‐fluorophenyl)pyrylium tetrafluoroborate (T( p ‐F)PPT) as the organocatalyst, and molecular oxygen as the green oxidant. During the transformation, T( p ‐F)PPT acts as both the electrophilic catalyst and photocatalyst, and the reaction is promoted by irradiation with visible light. The method introduced herein offers a straightforward route to the preparation of 1,2,4‐oxadiazolines with different functionalities, and is highly atom economical. magnified image" @default.
- W2802012809 created "2018-05-17" @default.
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- W2802012809 creator A5053371139 @default.
- W2802012809 creator A5086978843 @default.
- W2802012809 date "2018-05-22" @default.
- W2802012809 modified "2023-10-18" @default.
- W2802012809 title "Organocatalytic Oxidative Cyclization of Amidoximes for the Synthesis of 1,2,4‐Oxadiazolines" @default.
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- W2802012809 doi "https://doi.org/10.1002/adsc.201800238" @default.
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