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- W2802019997 abstract "Abstract The iron/diphosphine‐catalyzed annulation of a carboxamide possessing a bidentate directing group with an internal alkyne proceeds in the presence of phenylzinc halide as a base at 40 °C to produce a variety of indenone derivatives. The reaction proceeds through iron‐catalyzed C−H bond activation of the carboxamide, followed by insertion of the alkyne into the resulting iron intermediate, and cyclization accelerated by the presence of Lewis acidic Zn II . The reaction of naphthalene and anthraceneamide yields π‐conjugated indenone derivatives." @default.
- W2802019997 created "2018-05-17" @default.
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- W2802019997 date "2018-05-09" @default.
- W2802019997 modified "2023-10-14" @default.
- W2802019997 title "Iron-Catalyzed Synthesis of Indenones through Cyclization of Carboxamides with Alkynes" @default.
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- W2802019997 doi "https://doi.org/10.1002/ajoc.201800200" @default.
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