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- W2802023489 endingPage "79" @default.
- W2802023489 startingPage "60" @default.
- W2802023489 abstract "Ultrasmall (<2 nm) ligand-protected metal nanoclusters (NCs) have been an emerging class of functionalmaterials with rich coordination chemistry, finding increasing acceptance in both basic and appliedresearch owing to their atomic precision, well-defined molecular structure, and intriguing molecular-like properties. The presence of ligands on metal NCs is crucial not only for maintaining their atomic precision and well-defined structure, but also for their rich coordination chemistry with noble metals, influencing the synthesis, and physicochemical and catalytic properties of metal NCs. In this review, wediscuss the important roles of ligands to metal NCs, taking water-soluble gold nanoclusters (Au NCs)as an exampl e. The review covers the fundamental understandings (and advances) on the roles of ligandsto water-soluble Au NCs in the synthesis (e.g., influencing the size and formation rate, and revealing thegrowth mechanisms), physicochemical properties (e.g., geometrical structure, chirality, stability, solubility, and electronic, photoluminescence and biological properties) and catalytic applications (e.g., accessibility, activity, selectivity, and coordination of catalytic mechanism of quasi-homogeneous catalysts andimmobilization of heterogeneous catalysts). The review also highlights some challenging issues on howligands and ligand engineering could expand the scope of metal NCs in the synthesis, physicochemicalproperties, and catalytic application." @default.
- W2802023489 created "2018-05-17" @default.
- W2802023489 creator A5005348028 @default.
- W2802023489 creator A5060502332 @default.
- W2802023489 creator A5075696165 @default.
- W2802023489 creator A5082806907 @default.
- W2802023489 date "2018-08-01" @default.
- W2802023489 modified "2023-10-16" @default.
- W2802023489 title "Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters" @default.
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