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- W2802023679 abstract "New titanium phosphates were synthesized and tested as potential sorbents for europium from aqueous solutions. The experiments were undertaken in the concentration region 50–2000 mg L−1 at pH 5 without and with background electrolyte. The uptake data were determined by γ-spectroscopy with 152Eu as tracer and fitted by the Langmuir, Freundlich and Temkin models. The new materials showed high sorption capacities (up to 259.6 mg g−1) as derived from the Langmuir equation. Investigation of the sorption kinetics took place at 293, 303, 313 and 323 K. It was demonstrated that Eu-sorption proceeds very fast and described by pseudo-second-order kinetics while the rate constant and activation energy were calculated. Infrared and Raman spectroscopy, scanning electron microscopy and X-ray diffraction were applied for the sorbents characterization. Leaching tests were performed to assess the environmental compatibility of the loaded sorbent as well as desorption tests. The obtained data indicated that the interaction of the synthesized titanium phosphates with the Eu-solutions is a complex phenomenon based on ion exchange and formation of inner-sphere complexes." @default.
- W2802023679 created "2018-05-17" @default.
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- W2802023679 date "2018-04-01" @default.
- W2802023679 modified "2023-09-26" @default.
- W2802023679 title "Exploration of the parameters affecting the europium removal from aqueous solutions by novel synthesized titanium phosphates" @default.
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- W2802023679 doi "https://doi.org/10.1016/j.jece.2018.05.010" @default.
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