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- W2802043259 abstract "Abstract The ionic polyacetylenes (iPAs) with dendritic 1,2,3‐triazolium‐containing oligo(ethylene glycol) (OEG) pendants are prepared by metathesis cyclopolymerization. The dendritic triazolium and flexible OEG pendants endow the iPAs with low glass transition temperature of −29.0 °C and enhanced intrinsic ionic conductivity (σ i ) of 5.0 × 10 −5 S cm −1 at 30 °C under anhydrous conditions. After solution doping with bis(trifluoromethane)sulfonimide lithium (LiTFSI), the σ i of iPAs reaches up to 5.2 × 10 −4 S cm −1 . When doped with iodine (I 2 ), the iPAs exhibit high electronic conductivity (σ e ) of 1.3 × 10 −5 S cm −1 . If doped with both LiTFSI and I 2 , the iPAs demonstrate the best dual σ i and σ e of 8.3 × 10 −4 and 1.2 × 10 −5 S cm −1 , respectively. Therefore, the dendritic triazolium‐OEG pendants‐functionalized iPAs display an improved conductive performance compared with the corresponding iPAs bearing dendritic triazolium‐alkyl pendants, or branched triazolium‐OEG pendants, before and after doping with different dopants, and will have the potential applications in electronics as the dual conductive materials." @default.
- W2802043259 created "2018-05-17" @default.
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- W2802043259 date "2018-04-26" @default.
- W2802043259 modified "2023-10-14" @default.
- W2802043259 title "Enhanced Ionic and Electronic Conductivity of Polyacetylene with Dendritic 1,2,3-Triazolium-Oligo(ethylene glycol) Pendants" @default.
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- W2802043259 doi "https://doi.org/10.1002/macp.201800025" @default.
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