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• W2802067002 startingPage "5539" @default.
• W2802067002 abstract "Reduction of nitrobenzene by excess organic electron donor, 12, affords diphenylhydrazine in a reaction where azobenzene oxide and azobenzene are likely intermediates. No cleavage of the N-N σ-bond is seen under photoactivation conditions, whereas traces are seen under thermal activation. Hydrazone derivatives were prepared to explore the cleavage of N-N σ-bonds; the results show that a low-lying LUMO assists the transition state for accepting an electron, and the stabilisation that the potential fragments from N-N bond cleavage afford to the fragments is important in determining whether cleavage is observed." @default.
• W2802067002 created "2018-05-17" @default.
• W2802067002 creator A5036672552 @default.
• W2802067002 creator A5038338444 @default.
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• W2802067002 date "2018-09-01" @default.
• W2802067002 modified "2023-09-24" @default.
• W2802067002 title "Reduction of nitroarenes, azoarenes and hydrazine derivatives by an organic super electron donor" @default.
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• W2802067002 doi "https://doi.org/10.1016/j.tet.2018.04.069" @default.
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