Matches in SemOpenAlex for { <https://semopenalex.org/work/W2802094394> ?p ?o ?g. }
- W2802094394 endingPage "83" @default.
- W2802094394 startingPage "39" @default.
- W2802094394 abstract "To accurately comprehend the course of reaction progression, knowledge of kinetic parameters (triplet) is crucial, especially for complex reactions like biomass decomposition that is being researched for scale-up and process optimization. The techniques for kinetic analysis of biomass are more obscure compared with other solid-state reactions, owing to the complexity of the feed. This chapter presents a comprehension on the significance of kinetic triplet and evolution of various methods in pursuit of reliable kinetic parameters. Several reaction models have been described in the earlier sections of the chapter to explain the dependency of the rate of reaction as the function of conversion, models established on the assumption of the reaction mechanism, and models built on empirical fitting with little physical meanings. Too often, more than one of these models fits the experimental data, and more often, the reaction model changes with reaction progression in the case of biomass decomposition. An in-depth account has been provided on the early model-fitting methods, conventional single-heating rate-based nonisothermal methods, and modern isoconversional methods, with mathematical backgrounds and graphic illustrations, wherever applicable, for a better demonstration of their execution. Major stress has been laid on the isoconversional methods for kinetic analysis along with the contribution of ICTAC committee in their promotion. These methods are capable of working on the multistep reactions, involved in the thermal decomposition of assorted biomass mixture. However, since isoconversional methods do not yield the values of the preexponential factor and the reaction model, the methods for the consummation of kinetic triplet using the values of activation energy obtained from isoconversional methods have also been provided. A section has been devoted to “making kinetic predictions” from activation energy versus conversion dependencies in order to get a literal meaning of the mathematical data. Since energy production and energy saving is the key purpose behind all biomass conversion processes, a thermodynamic scenario has also been explicated in the later sections of the chapter. The knowledge of these thermodynamic parameters is indispensable and helps in understanding the changes in exothermicity/endothermicity, spontaneity, and reactivity of the reacting mixture, as reaction proceeds. Last but not the least, a computational perspective has also been provided, since all the methods for finding kinetic parameters are easier to execute with computational tools. It has been the best interest of the authors to embed this chapter with references to all the relevant work, which has been done in the field of kinetic analysis of biomass decomposition." @default.
- W2802094394 created "2018-05-17" @default.
- W2802094394 creator A5035074989 @default.
- W2802094394 creator A5035556283 @default.
- W2802094394 date "2018-01-01" @default.
- W2802094394 modified "2023-10-13" @default.
- W2802094394 title "Kinetic Analysis of Biomass Pyrolysis" @default.
- W2802094394 cites W1485730745 @default.
- W2802094394 cites W1618365190 @default.
- W2802094394 cites W1762398481 @default.
- W2802094394 cites W1772113289 @default.
- W2802094394 cites W1876658359 @default.
- W2802094394 cites W18923716 @default.
- W2802094394 cites W1963945460 @default.
- W2802094394 cites W1966439690 @default.
- W2802094394 cites W1969552050 @default.
- W2802094394 cites W1970807979 @default.
- W2802094394 cites W1973381749 @default.
- W2802094394 cites W1976624541 @default.
- W2802094394 cites W1978917587 @default.
- W2802094394 cites W1980958205 @default.
- W2802094394 cites W1988765610 @default.
- W2802094394 cites W1988991434 @default.
- W2802094394 cites W1996710156 @default.
- W2802094394 cites W1997245258 @default.
- W2802094394 cites W1998034560 @default.
- W2802094394 cites W2000140402 @default.
- W2802094394 cites W2000297458 @default.
- W2802094394 cites W2004793510 @default.
- W2802094394 cites W2005330689 @default.
- W2802094394 cites W2007711775 @default.
- W2802094394 cites W2008292329 @default.
- W2802094394 cites W2008854263 @default.
- W2802094394 cites W2009093385 @default.
- W2802094394 cites W2011806614 @default.
- W2802094394 cites W2011897767 @default.
- W2802094394 cites W2012257367 @default.
- W2802094394 cites W2017043259 @default.
- W2802094394 cites W2017636120 @default.
- W2802094394 cites W2019425143 @default.
- W2802094394 cites W2023987499 @default.
- W2802094394 cites W2024908520 @default.
- W2802094394 cites W2025006200 @default.
- W2802094394 cites W2025553984 @default.
- W2802094394 cites W2028316962 @default.
- W2802094394 cites W2028619870 @default.
- W2802094394 cites W2029842684 @default.
- W2802094394 cites W2034002625 @default.
- W2802094394 cites W2035188328 @default.
- W2802094394 cites W2041826578 @default.
- W2802094394 cites W2048143726 @default.
- W2802094394 cites W2048964735 @default.
- W2802094394 cites W2050448806 @default.
- W2802094394 cites W2056313043 @default.
- W2802094394 cites W2059161112 @default.
- W2802094394 cites W2061120395 @default.
- W2802094394 cites W2063347462 @default.
- W2802094394 cites W2065200382 @default.
- W2802094394 cites W2065939768 @default.
- W2802094394 cites W2068641126 @default.
- W2802094394 cites W2069153838 @default.
- W2802094394 cites W2070867152 @default.
- W2802094394 cites W2072213552 @default.
- W2802094394 cites W2073579653 @default.
- W2802094394 cites W2079300103 @default.
- W2802094394 cites W2083275521 @default.
- W2802094394 cites W2083791082 @default.
- W2802094394 cites W2084777440 @default.
- W2802094394 cites W2085232207 @default.
- W2802094394 cites W2090573029 @default.
- W2802094394 cites W2091857923 @default.
- W2802094394 cites W2094349390 @default.
- W2802094394 cites W2105282439 @default.
- W2802094394 cites W2113221689 @default.
- W2802094394 cites W2133320229 @default.
- W2802094394 cites W2143903688 @default.
- W2802094394 cites W2158092432 @default.
- W2802094394 cites W2159440735 @default.
- W2802094394 cites W2168187302 @default.
- W2802094394 cites W2213780863 @default.
- W2802094394 cites W2318742334 @default.
- W2802094394 cites W2587551625 @default.
- W2802094394 cites W2752443178 @default.
- W2802094394 cites W4244844037 @default.
- W2802094394 cites W4253850866 @default.
- W2802094394 cites W4255458428 @default.
- W2802094394 cites W4379982368 @default.
- W2802094394 doi "https://doi.org/10.1016/b978-0-444-63992-9.00002-1" @default.
- W2802094394 hasPublicationYear "2018" @default.
- W2802094394 type Work @default.
- W2802094394 sameAs 2802094394 @default.
- W2802094394 citedByCount "20" @default.
- W2802094394 countsByYear W28020943942019 @default.
- W2802094394 countsByYear W28020943942020 @default.
- W2802094394 countsByYear W28020943942021 @default.
- W2802094394 countsByYear W28020943942022 @default.
- W2802094394 countsByYear W28020943942023 @default.
- W2802094394 crossrefType "book-chapter" @default.