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- W2802095997 abstract "We show here that optically active cryptophane 1 bearing phenol functions can efficiently bind the two enantiomers of 2‐(chloromethyl)oxirane, ethyloxirane, and 2,2′‐bioxirane derivatives in aqueous solution. The binding process is characterized by high‐field 1 H NMR signals that are specific to the encapsulated species. In all cases, an enantioselective effect was observed and a relationship between the molecular volume of the guest and the binding constant can be established, even though the flexibility of the guest molecule also seems to play a role. In this series, the 2,2′‐bioxirane guest is a particularly interesting example, because this compound possesses two stereogenic centers. Thus, in solution, three different pairs of enantiomers can be obtained in the presence of the optically active host 1 . Electronic circular dichroism (ECD) spectroscopy has also been used to characterize these complexes; specific ECD spectra recorded in the 1 L b region were obtained for each diastereomer." @default.
- W2802095997 created "2018-05-17" @default.
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- W2802095997 date "2018-04-09" @default.
- W2802095997 modified "2023-10-03" @default.
- W2802095997 title "Enantioselective Complexation of Chiral Oxirane Derivatives by an Enantiopure Cryptophane in Water" @default.
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- W2802095997 doi "https://doi.org/10.1002/ejoc.201800142" @default.
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