Matches in SemOpenAlex for { <https://semopenalex.org/work/W2802295964> ?p ?o ?g. }
- W2802295964 endingPage "4489" @default.
- W2802295964 startingPage "4480" @default.
- W2802295964 abstract "Abstract The temperature dependent rate coefficients for the reaction between 2,2,2‐trifluoroethylbutyrate (2,2,2‐TFEB) with OH radicals were measured as a function of temperature (268‐343 K) and pressure (400‐760 Torr; N 2 and O 2 ) using relative rate technique. The temperature dependent rate coefficients for the gas phase reaction of 2,2,2‐TFEB + OH were used to deduce the Arrhenius expression: k(268‐343 K) = (2.72 ± 1.3)×10 −13 exp{(530± 72)/T}cm 3 molecule −1 s −1 . At 298 K, the rate coefficient for the title reaction was obtained to be (1.58 ± 0.42) ×10 −12 cm 3 molecule −1 s −1 . Extensive computational calculations were also performed as a complement to the present experimental study using canonical variational transition state theory (CVT) with small curvature tunnelling (SCT) correction in combination with the CCSD(T)/CC‐PVDZ//M062X/6‐31+G(d,p) level of theory. The atmospheric lifetime of the test molecule due to its reaction with OH radical is about 3 days, which is short lived. And therefore, its contribution towards the global warming potentials can be insignificant. The ozone formation potential of the test molecule is calculated to be 0.229 ppm, which is again negligible." @default.
- W2802295964 created "2018-05-17" @default.
- W2802295964 creator A5040934610 @default.
- W2802295964 creator A5048311256 @default.
- W2802295964 creator A5080760440 @default.
- W2802295964 date "2018-04-25" @default.
- W2802295964 modified "2023-09-27" @default.
- W2802295964 title "Kinetic Investigations on the Gas Phase Reaction of 2,2,2-Trifluoroethylbutyrate with OH Radicals: An Experimental and Theoretical Study" @default.
- W2802295964 cites W1424125451 @default.
- W2802295964 cites W1593655292 @default.
- W2802295964 cites W1969834329 @default.
- W2802295964 cites W1972441047 @default.
- W2802295964 cites W1978347469 @default.
- W2802295964 cites W1980208270 @default.
- W2802295964 cites W1989168486 @default.
- W2802295964 cites W1991813168 @default.
- W2802295964 cites W1994334343 @default.
- W2802295964 cites W1994382421 @default.
- W2802295964 cites W1997561328 @default.
- W2802295964 cites W2014562537 @default.
- W2802295964 cites W2029496123 @default.
- W2802295964 cites W2030170689 @default.
- W2802295964 cites W2035194227 @default.
- W2802295964 cites W2043287265 @default.
- W2802295964 cites W2046068099 @default.
- W2802295964 cites W2046689204 @default.
- W2802295964 cites W2051563761 @default.
- W2802295964 cites W2054230964 @default.
- W2802295964 cites W2057327625 @default.
- W2802295964 cites W2067342499 @default.
- W2802295964 cites W2074061861 @default.
- W2802295964 cites W2074767518 @default.
- W2802295964 cites W2075275205 @default.
- W2802295964 cites W2080261105 @default.
- W2802295964 cites W2081525194 @default.
- W2802295964 cites W2082953446 @default.
- W2802295964 cites W2091501238 @default.
- W2802295964 cites W2094522931 @default.
- W2802295964 cites W2118813607 @default.
- W2802295964 cites W2315824375 @default.
- W2802295964 cites W2401460598 @default.
- W2802295964 cites W2577543771 @default.
- W2802295964 cites W2639828598 @default.
- W2802295964 cites W2724526871 @default.
- W2802295964 cites W2951697125 @default.
- W2802295964 cites W574766916 @default.
- W2802295964 doi "https://doi.org/10.1002/slct.201703113" @default.
- W2802295964 hasPublicationYear "2018" @default.
- W2802295964 type Work @default.
- W2802295964 sameAs 2802295964 @default.
- W2802295964 citedByCount "2" @default.
- W2802295964 countsByYear W28022959642022 @default.
- W2802295964 crossrefType "journal-article" @default.
- W2802295964 hasAuthorship W2802295964A5040934610 @default.
- W2802295964 hasAuthorship W2802295964A5048311256 @default.
- W2802295964 hasAuthorship W2802295964A5080760440 @default.
- W2802295964 hasConcept C113196181 @default.
- W2802295964 hasConcept C121332964 @default.
- W2802295964 hasConcept C135889238 @default.
- W2802295964 hasConcept C139066938 @default.
- W2802295964 hasConcept C147597530 @default.
- W2802295964 hasConcept C147789679 @default.
- W2802295964 hasConcept C148898269 @default.
- W2802295964 hasConcept C178790620 @default.
- W2802295964 hasConcept C185592680 @default.
- W2802295964 hasConcept C3020013744 @default.
- W2802295964 hasConcept C32909587 @default.
- W2802295964 hasConcept C62520636 @default.
- W2802295964 hasConcept C86183883 @default.
- W2802295964 hasConcept C93391505 @default.
- W2802295964 hasConcept C95121573 @default.
- W2802295964 hasConcept C97355855 @default.
- W2802295964 hasConceptScore W2802295964C113196181 @default.
- W2802295964 hasConceptScore W2802295964C121332964 @default.
- W2802295964 hasConceptScore W2802295964C135889238 @default.
- W2802295964 hasConceptScore W2802295964C139066938 @default.
- W2802295964 hasConceptScore W2802295964C147597530 @default.
- W2802295964 hasConceptScore W2802295964C147789679 @default.
- W2802295964 hasConceptScore W2802295964C148898269 @default.
- W2802295964 hasConceptScore W2802295964C178790620 @default.
- W2802295964 hasConceptScore W2802295964C185592680 @default.
- W2802295964 hasConceptScore W2802295964C3020013744 @default.
- W2802295964 hasConceptScore W2802295964C32909587 @default.
- W2802295964 hasConceptScore W2802295964C62520636 @default.
- W2802295964 hasConceptScore W2802295964C86183883 @default.
- W2802295964 hasConceptScore W2802295964C93391505 @default.
- W2802295964 hasConceptScore W2802295964C95121573 @default.
- W2802295964 hasConceptScore W2802295964C97355855 @default.
- W2802295964 hasFunder F4320321026 @default.
- W2802295964 hasIssue "16" @default.
- W2802295964 hasLocation W28022959641 @default.
- W2802295964 hasOpenAccess W2802295964 @default.
- W2802295964 hasPrimaryLocation W28022959641 @default.
- W2802295964 hasRelatedWork W1967314609 @default.
- W2802295964 hasRelatedWork W1989071799 @default.
- W2802295964 hasRelatedWork W1999977692 @default.
- W2802295964 hasRelatedWork W2059109447 @default.
- W2802295964 hasRelatedWork W2105103143 @default.